16654-74-3 (双[2-(三甲基硅氧基)乙基]醚,bis2-(Trimethylsilyloxy)ethyl Ether)

CAS号:
16654-74-3
中文名称:
双[2-(三甲基硅氧基)乙基]醚
英文名称:
bis2-(Trimethylsilyloxy)ethyl Ether
分子式:
C10H26O3Si2
分子量:
250.482645511627

双[2-(三甲基硅氧基)乙基]醚(16654-74-3)名称与标识符

名称

中文别名:
双[2-(三甲基硅氧基)乙基]醚;双[2-(三甲基甲硅烷基氧基)乙基] 醚;双[2-(三甲基硅氧基)乙基]乙醚;BIS[2-(TRIMETHYLSILYLOXY)ETHYL] ETHER; 双[2-(三甲基硅氧基)乙基]醚;
英文别名:
trimethyl-[2-(2-trimethylsilyloxyethoxy)ethoxy]silane;Bis[2-(trimethylsilyloxy)ethyl] Ether;ACMC-209dup;1-{2-[2-(1,1-dimethyl-1-silaethoxy)ethoxy]ethoxy}-1,1-dimethyl-1-silaethane;bis(2-trimethylsiloxyethyl)ether;O,O-bis(2-trimethylsilyl)diethyleneglycol;AR-1D0209;Diethylene glycol, bistrimethylsilyl ether;2,2,10,10-Tetramethyl-3,6,9-trioxa-2,10-disilaundecane;ANW-22223;CTK4D2380;AC1LB7NN;AC1Q55JY;BIS[2-(TRIMETHYLSILOXY)ETHYL] ETHER;Diethylene Glycol Bis(trimethylsilyl Ether);VZCNNAQIFXLAEZ-UHFFFAOYSA-N;Diethylene glycol, 2TMS derivative;bis(2-trimethyl-siloxyethyl) ether;Diethylene Glycol Bis(;AS-70126;DTXSID10339035;B3378;3,6,9-Trioxa-2,10-disilaundecane, 2,2,10,10-tetramethyl-;16654-74-3;AKOS015839980;MFCD11975427;SCHEMBL10529106;Bis[2-(trimethylsilyloxy)ethyl]ether;D89011;DB-250795;NS00113909;

标识符

MDL:
MFCD11975427
InChIKey:
VZCNNAQIFXLAEZ-UHFFFAOYSA-N
Inchi:
1S/C10H26O3Si2/c1-14(2,3)12-9-7-11-8-10-13-15(4,5)6/h7-10H2,1-6H3
SMILES:
[Si](C)(C)(C)OCCOCCO[Si](C)(C)C

双[2-(三甲基硅氧基)乙基]醚(16654-74-3)物化性质

实验特性

  • LogP : 2.70600
  • PSA : 27.69000
  • 折射率 : 1.4130-1.4170
  • 沸点 : 87°C/5mmHg(lit.)
  • 熔点 : No data available
  • 蒸气压 : 0.2±0.4 mmHg at 25°C
  • 闪点 : 72.4±20.8 °C
  • 颜色与性状 : No data available
  • 密度 : 0.9±0.1 g/cm3

计算特性

  • 精确分子量 : 250.14200
  • 氢键供体数量 : 0
  • 氢键受体数量 : 3
  • 可旋转化学键数量 : 8
  • 同位素质量 : 250.14204776g/mol
  • 重原子数量 : 15
  • 复杂度 : 143
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 拓扑分子极性表面积 : 27.7

双[2-(三甲基硅氧基)乙基]醚(16654-74-3)海关数据

海关编码:
2931900090
海关数据:

中国海关编码:

2931900090

概述:

2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

Summary:

2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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双[2-(三甲基硅氧基)乙基]醚(16654-74-3)上下游

双[2-(三甲基硅氧基)乙基]醚(16654-74-3)参考资料

Reaxys RN:
4175554
Beilstein:
B152543
PubChem CID:

双[2-(三甲基硅氧基)乙基]醚(16654-74-3) MSDS

基础信息

  Bis[2-(trimethylsilyloxy)ethyl] Ether      Revision number: 1    
  SAFETY DATA SHEET

Section 1. BASE INFORMATION
  Product name:        Bis[2-(trimethylsilyloxy)ethyl] Ether    

  Revision number:        1    

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS
  Flammable liquids        Category 4    
    Not classified
  HEALTH HAZARDS
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements
  Pictograms or hazard symbols        None    
    Warning
  Signal word
  Hazard statement        Combustible liquid    
  Precautionary statements
  [Prevention]        Keep away from flames and hot surfaces.    
    Wear protective gloves and eye/face protection.
  [Storage]        Store in a well-ventilated place. Keep cool.    
    Dispose of contents/container through a waste management company authorized by
  [Disposal]
    the local government

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Component(s):        Bis[2-(trimethylsilyloxy)ethyl] Ether    
  Percent:        >98.0%(GC)    
    16654-74-3
  CAS Number:
  Synonyms:        Diethylene Glycol Bis(trimethylsilyl Ether)    
  Chemical Formula:        C10H26O3Si2    

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with    
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
    Rinse cautiously with water for several minutes. Remove contact lenses, if present
  Eye contact:
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.    
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.
  Bis[2-(trimethylsilyloxy)ethyl] Ether

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, carbon dioxide.    
  media:
  Extinguishing media not to Water (It may scatter and spread fire.)
  be used:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to    
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing    
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
  hazards:        case of a fire. Use spark-proof tools and explosion-proof equipment.    

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent generation of vapor or mist. Keep away from flames and hot surfaces. Take
    measures to prevent the build up of electrostatic charge. Use explosion-proof
    equipment. Wash hands and face thoroughly after handling.
    Use a closed system, ventilation.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.    
  Storage
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.    
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Law is followed.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust as possible so that workers should not be
  Engineering controls:
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Vapor respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
  Eye protection:        Safety glasses. A face-shield, if the situation requires.    
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
  Form:        clear    
  Color:        Colorless - Almost colorless    
  Odor:        No data available    
  pH: No data available
  Melting point/freezing point:No data available
    87 °C/0.7kPa
  Boiling Point/Range:
  Flash Point:        No data available    
  Bis[2-(trimethylsilyloxy)ethyl] Ether

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Explosive limits
    No data available
  Lower:
  Upper:        No data available    
    0.89
  Density:
  Solubility:        No data available    

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.    
  Reactivity:        No special reactivity has been reported.    
  Incompartible materials: oxidizing agents
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Silicon oxides
  Products:

Section 11. TOXICOLOGICAL INFORMATION
    No data available
  Acute Toxicity:
  Skin corrosion/irritation: No data available
    No data available
  Serious eye
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available    
    No data available
  Reproductive toxicity:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
  Algae:        No data available    
  Persistence / degradability: No data available
  Bioaccumulative        No data available    
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
  UN-No:        Not Listed    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.
  Bis[2-(trimethylsilyloxy)ethyl] Ether


SECTION 16 - ADDITIONAL INFORMATION
N/A