210842-74-3 ((αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁,(Alphar,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(diphenylphosphino)ferrocene)

快速询单

结构式：

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁MOL文件

CAS号：

210842-74-3

中文名称：

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁

英文名称：

(Alphar,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(diphenylphosphino)ferrocene

分子式：

C₅₂H₅₀FeN₂P₂

分子量：

820.75933599472

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁(210842-74-3)名称与标识符

名称

中文别名：

(2S,2'S)-1,1'-双((R)-(二甲基氨基)苯基甲基)-2,2'-双(二苯基膦)二茂铁;(S,S)-(-)-2,2'-双[-(N,N-二甲胺基)(苯基)甲基]-1,1'-双(二苯基磷)二茂铁;(S,S)-(-)-2,2'-双[?-(N,N-二甲胺基)(苯基)甲基]-1,1'-双(二苯基磷)二茂铁;(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁;(2S,2'S)-1,1'-双[(R)-(二甲基氨基)苯基甲基]-2,2'-双(二苯基膦)二茂铁;(AR,AR)-2,2'-双(A-N,N-二甲基氨基苯甲基)-(S,S)-1,1'-双(二苯基膦基)二茂铁;(2R,2′R)-1,1′-双[(R)-(二甲氨基)苯基甲基]-2,2′-双(二苯基膦)二茂铁(根据 CAS);(2S,2'S)-1,1'-双[(R)-(二甲基氨基)苯基甲基]-2,2'-双(二苯基膦基)二茂铁;(S,S)-(-)-2,2'-双[(R)-(N,N-二甲胺基)(苯基)甲基]-1,1'-双(二苯基磷)二茂铁(双侧点手性均为R);(S,S)-(-)-2,2'-双[(R)-(N,N-二甲基氨基)(苯基)甲基]-1,1'-双(二苯基膦基)二茂铁;(ALPHAR,ALPHAR)-2,2-双(ALPHA-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁;

英文别名：

Ferrocene,1,1'-bis[(R)-(dimethylamino)phenylmethyl]-2,2'-bis(diphenylphosphino)-,(2S,2'S)-;(1S)-1-(2-diphenylphosphanylcyclopentyl)-N,N-dimethyl-1-phenylmethanamine,iron;(2S,2 inverted exclamation markaS)-1,1 inverted exclamation marka-Bis[(S)-(dimethylamino)phenylmethyl]-2,2 inverted exclamation marka-bis(diphenylphosphino)ferrocene (acc to );A-(dimethylamino)benzyl]-2,2 inverted exclamation marka-bis(diphenylphosphino)ferrocene;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene;(SP,S'P)-1,1'-Bis[(R)-alpha-(dimethylamino)benzyl]-2,2'-bis(diphenylphosphino)ferrocene;SC11401;(AR,AR)-2,2'-BIS(A-N,N-DIMETHYLAMINOPHENYLMETHYL)-(S,S)-1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE;(ALP;(Alphar,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis(diphenylphosphino)ferrocene;MANDYPHOS SL-M001-1;(R,R)-1,1'-BIS[(R)-ALPHA-(DIMETHYLAMINO)PHENYLMETHYL]-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE;(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene,min.97%;(SP,SμP)-1,1μ-Bis[(R)-α-(dimethylamino)benzyl]-2,2μ-bis(diphenylphosphino)ferrocene;Mandyphos SL-M001-1, (2R,2μR)-1,1μ-Bis[(R)-(dimethylamino)phenylmethyl]-2,2μ-bis(diphenylphosphino)ferrocene (acc to CAS);(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl) methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%;(aR,aR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)-1,1'-bis(diphenylphosphino)ferrocene;

标识符

MDL：

MFCD04117705

InChIKey：

HZATWRYPFZEGHM-PMIUFOJNSA-N

Inchi：

1S/2C26H25NP.Fe/c2*1-27(2)26(21-13-6-3-7-14-21)24-19-12-20-25(24)28(22-15-8-4-9-16-22)23-17-10-5-11-18-23;/h2*3-20,26H,1-2H3;/t2*26-;/m11./s1

SMILES：

[C]1([CH][CH][CH][C]1P(C1C=CC=CC=1)C1C=CC=CC=1)[C@@H](C1C=CC=CC=1)N(C)C.[C]1([CH][CH][CH][C]1P(C1=CC=CC=C1)C1C=CC=CC=1)[C@@H](C1=CC=CC=C1)N(C)C.[Fe]

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁(210842-74-3)物化性质

实验特性

LogP : 9.73510
PSA : 33.66000

计算特性

精确分子量 : 820.28000
氢键供体数量 : 0
氢键受体数量 : 2
可旋转化学键数量 : 12
重原子数量 : 57
复杂度 : 427
拓扑分子极性表面积 : 6.5

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁(210842-74-3)安全信息

储存条件： Inert atmosphere,Room Temperature

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁(210842-74-3)海关数据

海关编码：

29319090

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁(210842-74-3)推荐厂家更多厂家(15)

公司名称	手机号/电话	联系人	QQ	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单
江苏雷恩环保科技有限公司	18662920632 0513-66017275	费小姐	3485543679	询单
上海绩祥生物科技有限公司	13093077543	陆经理	3985448220	询单
武汉鑫伟烨化工有限公司	18502781673 027-18502781673	张经理	359501377	询单
上海腾准生物科技有限公司	19821570922 021-34053661	张经理	3003871136	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单
上海麦克林生化科技股份有限公司	15221275939 021-50706066	沈经理	269348414	询单

(αR,αR)-2,2-双(α-N,N-二甲氨基苯基甲基)-(S,S)-1,1-双(二苯基膦)二茂铁(210842-74-3) MSDS

基础信息

Section 1: Product Identification
   Chemical Name:       (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene, min. 97%
   CAS Registry Number:       210842-74-3
   Formula:       C52H50FeN2P2
   EINECS Number:       None
   Chemical Family:       organophosphine ligand
   Synonym:       none

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 210842-74-3 100% no data no data

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and mucous membranes. May be harmful if swallowed.
   Primary Routes of Exposure:       Ingestion, eyes
   Eye Contact:       Causes slight to mild irritation of the eyes.
   Skin Contact:       Causes slight to mild irritation of the skin.
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.
   Ingestion:       No information available on the physiological effects of ingestion.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.
   The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
   Chronic Health Affects:
   may be present.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, foam or dry powder
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Keep material in a tightly sealed container. Prolonged exposure to the air may result in degradation of the
   Handling and Storage:
   product. Handle and store material under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear protective clothing and gloves.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       orange-red solid
   Molecular Weight:       820.76
   Melting Point:       no data
   Boiling Point:       no data
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       Insoluble

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       exposure to oxygen, contact with strong oxidizing agents
   Incompatibility:       Oxidizing agents and halogens
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, phosphorus oxides, nitrogen oxides and iron oxide.

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       No data
   Mutagenic Effects:       No data
   Tetratogenic Effects:       No data

SECTION 12: Ecological Information
Ecological Information: No information available

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.
   SARA (Title 313):       Title compound not listed.
   Second Ingredient:       None

SECTION 16 - ADDITIONAL INFORMATION
N/A