26214-68-6 (1-甲基吡咯-2-羰酰氯,1-Methylpyrrole-2-carbonylchloride)

CAS号:
26214-68-6
中文名称:
1-甲基吡咯-2-羰酰氯
英文名称:
1-Methylpyrrole-2-carbonylchloride
分子式:
C6H6ClNO
分子量:
143.570940494537

1-甲基吡咯-2-羰酰氯(26214-68-6)名称与标识符

名称

中文别名:
1-甲基吡咯-2-羰酰氯;1-甲基吡咯-2-甲酰氯;1-甲基-1H-吡咯-2-甲酰氯;1-甲基-1H-吡咯-2-羰酰氯;
英文别名:
1-Methylpyrrole-2-carbonyl chloride;1-Methyl-1H-pyrrole-2-carbonyl chloride;1H-Pyrrole-2-carbonyl chloride, 1-methyl-;1-methy-1H-pyrrole-2-carbonyl chloride;1-methyl-2-pyrrole-carbonyl chloride;1-methyl-2-pyrrolecarboxylic acid chloride;1-methylpyrrol-2-carboxylic acid chloride;1-methyl-pyrrole-2-carboxylic acid chloride;N-methylpyrrole-2-carbonyl chloride;Pyrrole-2-carbonylchloride, 1-methyl- (8CI);1-Methyl-1H-pyrrole-2-carboxylic acid chloride;1-Methyl-2-pyrrolylcarbonylchloride;N-Methylpyrrole-2-carbonylchloride;1-methyl-2-pyrroyl chloride;E74234;N-methylpyrrole carbonyl chloride;FT-0608095;N-methyl-2-pyrroloyl chloride;AS-65245;MFCD02094021;J-504903;1-methylpyrrole-2-carboyl chloride;AKOS006230187;1-methylpyrrole-2-carbonylchloride;2-(Chlorocarbonyl)-1-methyl-1H-pyrrole;N-methylpyrrol-2-carboxylic acid chloride;26214-68-6;SCHEMBL194181;N-methylpyrrolecarbonyl chloride;DTXSID40383541;JOYDZQJINHJNPM-UHFFFAOYSA-N;

标识符

MDL:
MFCD02094021
InChIKey:
JOYDZQJINHJNPM-UHFFFAOYSA-N
Inchi:
1S/C6H6ClNO/c1-8-4-2-3-5(8)6(7)9/h2-4H,1H3
SMILES:
ClC(C1=CC=CN1C)=O
BRN:
472022

1-甲基吡咯-2-羰酰氯(26214-68-6)物化性质

实验特性

  • LogP : 1.40410
  • PSA : 22.00000
  • 折射率 : 1.5700
  • 水溶性 : Reacts with water.
  • 沸点 : 78 ºC (15 mmHg)
  • 闪点 : 72-74°C/10mm
  • 颜色与性状 : 未确定
  • 溶解性 : 未确定
  • 敏感性 : Moisture Sensitive
  • 密度 : 1.22

计算特性

  • 精确分子量 : 143.01400
  • 氢键供体数量 : 0
  • 氢键受体数量 : 2
  • 可旋转化学键数量 : 1
  • 同位素质量 : 143.014
  • 重原子数量 : 9
  • 复杂度 : 126
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 1.5
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 22A^2

1-甲基吡咯-2-羰酰氯(26214-68-6)安全信息

1-甲基吡咯-2-羰酰氯(26214-68-6)国际标准相关数据

EINECS:
000-000-0

1-甲基吡咯-2-羰酰氯(26214-68-6)海关数据

海关编码:
2933990090
海关数据:

中国海关编码:

2933990090

概述:

2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素:

品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期

Summary:

2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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1-甲基吡咯-2-羰酰氯(26214-68-6) MSDS

基础信息

Name:1-Methyl-1H-pyrrole-2-carbonyl chloride 97% Material Safety Data Sheet
Synonym:
CAS:26214-68-6
Section 1 - Chemical Product ? MSDS Name:1-Methyl-1H-pyrrole-2-carbonyl chloride 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
26214-68-61-Methyl-1H-pyrrole-2-carbonyl chlorid97%unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
? Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 26214-68-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Liquid
Color: brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 84 deg C @15mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H6ClNO
Molecular Weight: 143.57

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 26214-68-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Methyl-1H-pyrrole-2-carbonyl chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 26214-68-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 26214-68-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 26214-68-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A