32974-36-0 (五氟碘苯,Pentafluorobenzyl Toluene-4-sulfonate)

快速询单

结构式：

五氟碘苯MOL文件

CAS号：

32974-36-0

中文名称：

五氟碘苯

英文名称：

Pentafluorobenzyl Toluene-4-sulfonate

分子式：

C₁₄H₉F₅O₃S

分子量：

352.276480436325

简介：

五氟碘苯，一种有机化学物质，分子式：C6F5I。

五氟碘苯(32974-36-0)名称与标识符

名称

中文别名：

对甲苯磺酸五氟苄酯[用于无机阴离子的气相色谱的诱导试剂];对甲苯磺酸五氟苄酯;五氟碘苯;(全氟苯基)4-甲基苯磺酸甲酯;

英文别名：

Benzenemethanol,2,3,4,5,6-pentafluoro-, 1-(4-methylbenzenesulfonate);Pentafluorobenzyl p-Toluenesulfonate [Derivatizing Reagent for GC of Inorganic Anions];(2,3,4,5,6-pentafluorophenyl)methyl 4-methylbenzenesulfonate;2,3,4,5,6-Pentafluorbenzyl-toluol-p-sulfonat;PC5557E;Pentafluorobenzyl 4-methylbenzenesulphonate;Pentafluorobenzyl p-Toluenesulfonate;Pentafluorobenzyl toluene-4-sulphonate;Pentafluorobenzyl tosylate;PFB-Tosylate;p-Toluenesulfonic Acid Pentafluorobenzyl Ester;PFB - Tosylate;Pentafluorobenzyl toluene-4-sulfonate;4-methylbenzenesulfonic acid [difluoro-(2,3,4-trifluorophenyl)methyl] ester;p-Toluenesulfonic acid pentafluorophenylmethyl ester;Der;Pentafluorobenzyl toluene-4-sulphonate 98%;Pentafluorobenzyl 4-methylbenzenesulphonate, Pentafluorobenzyl tosylate;PFB - Tosylate p-Toluenesulfonic Acid Pentafluorobenzyl Ester;MFCD06248628;perfluorobenzyl 4-methylbenzenesulfonate;(Perfluorophenyl)methyl4-methylbenzenesulfonate;(Perfluorophenyl)methyl 4-methylbenzenesulfonate;SCHEMBL776071;T1204;32974-36-0;(pentafluorophenyl)methyl 4-methylbenzene-1-sulfonate;AKOS027383396;p-Toluenesulfonicacidpentafluorobenzylester;A821537;DTXSID80379746;FS-5854;T72308;FT-0639071;2,3,4,5,6-Pentafluorobenzyl p-toluenesulfonate;Pentafluorbenzyl-p-toluolsulfonat;Benzenemethanol, 2,3,4,5,6-pentafluoro-, 4-methylbenzenesulfonate;BKNSDBYJUGNUDL-UHFFFAOYSA-N;DB-048306;

标识符

MDL：

MFCD06248628

InChIKey：

BKNSDBYJUGNUDL-UHFFFAOYSA-N

Inchi：

1S/C14H9F5O3S/c1-7-2-4-8(5-3-7)23(20,21)22-6-9-10(15)12(17)14(19)13(18)11(9)16/h2-5H,6H2,1H3

SMILES：

S(C1C=CC(C)=CC=1)(=O)(=O)OCC1C(=C(C(=C(C=1F)F)F)F)F

五氟碘苯(32974-36-0)物化性质

实验特性

LogP : 4.67680
PSA : 51.75000
折射率 : 1.521
沸点 : 395.4±42.0 °C at 760 mmHg
熔点 : 76.0 to 79.0 deg-C
蒸气压 : 0.0±0.9 mmHg at 25°C
闪点 : 192.9±27.9 °C
颜色与性状 : 未确定
溶解性 : 未确定
密度 : 1.5±0.1 g/cm3

计算特性

精确分子量 : 352.01900
氢键供体数量 : 0
氢键受体数量 : 3
可旋转化学键数量 : 4
同位素质量 : 352.019
重原子数量 : 23
复杂度 : 473
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 3.6
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 51.8A^2

五氟碘苯(32974-36-0)安全信息

安全说明： S26-S36
风险术语： R36/37/38
危险品标志： Xi
危害声明：Irritant
警示性声明：P264+P280+P305+P351+P338+P337+P108
储存条件： 4℃条件下存储,-4℃存储更佳
危险类别码： 36/37/38
信号词： warning
HazardClass： IRRITANT

五氟碘苯(32974-36-0)国际标准相关数据

EINECS：

87576985

五氟碘苯(32974-36-0)海关数据

海关编码：

2906299090

海关数据：

中国海关编码：

2906299090

概述：

2906299090 其他芳香醇. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途

Summary：

2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

五氟碘苯(32974-36-0)推荐厂家更多厂家(12)

公司名称	手机号/电话	联系人	QQ	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
上海依赫生物科技有限公司	17721395025 021-68882955	张经理	2423903095	询单
JACS-郑州杰克斯化工产品有限公司	15981966935 0371-86259281	杰克斯JACS	893596907	询单
广东翁江化学试剂有限公司	13927875076 0751-2815987	罗雪云	3007432263	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单
广东科源化工有限公司	19928588395 0751-2819818	陈经理	3967494957	询单
上海麦克林生化科技股份有限公司	15221275939 021-50706066	沈经理	269348414	询单
梯希爱（上海）化成工业发展有限公司	13061970904	张泽原	862682778	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单

五氟碘苯(32974-36-0)相关文献

1. Atomic spectrometry update. Atomic mass spectrometry
Jeffrey R. Bacon,Kathryn L. Linge,Randall R. Parrish,Luc Van Vaeck J. Anal. At. Spectrom. 2006 21 785

五氟碘苯(32974-36-0)参考资料

Reaxys RN：

2400288

Beilstein：

P160259

PubChem CID：

87576985

五氟碘苯(32974-36-0) MSDS

基础信息

  Pentafluorobenzyl p-Toluenesulfonate [Derivatizing      Revision number: 5
  Reagent for GC of Inorganic Anions]
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Pentafluorobenzyl p-Toluenesulfonate [Derivatizing Reagent for GC of Inorganic
    Anions]

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
    Not classified
  PHYSICAL HAZARDS
  HEALTH HAZARDS        Not classified
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols        None
  Signal word        No signal word
  Hazard statements        None
  Precautionary statements:        None

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
    Pentafluorobenzyl p-Toluenesulfonate [Derivatizing Reagent for GC of Inorganic
  Components:
    Anions]
    >98.0%(T)
  Percent:
  CAS Number:        32974-36-0
    PFB - Tosylate , p-Toluenesulfonic Acid Pentafluorobenzyl Ester
  Synonyms:
  Chemical Formula:        C14H9F5O3S

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
    Get medical advice/attention if you feel unwell. Rinse mouth.
  Ingestion:
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water spray, carbon dioxide.
  Suitable extinguishing
  media:
  Pentafluorobenzyl p-Toluenesulfonate
  [Derivatizing Reagent for GC of Inorganic
  Anions]

Section 5. FIRE-FIGHTING MEASURES
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust as possible so that workers should not be
  Engineering controls:
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
    Protective gloves.
  Hand protection:
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
  Form:        Crystal- Powder
    White - Almost white
  Colour:
  Odour:        No data available
  pH: No data available
  Melting point/freezing point:78°C
    No data available
  Boiling point/range:
  Flash point:        No data available
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        No data available
  Solubility(ies):
    No data available
  [Water]
  Pentafluorobenzyl p-Toluenesulfonate
  [Derivatizing Reagent for GC of Inorganic
  Anions]

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
[Other solvents]
Soluble: Methanol

Section 10. STABILITY AND REACTIVITY
    Stable under proper conditions.
  Chemical stability:
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride, Sulfur oxides
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  NTP =        No data available
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
    No data available
  Crustacea:
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
    No data available
  Henry's Law
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Pentafluorobenzyl p-Toluenesulfonate
  [Derivatizing Reagent for GC of Inorganic
  Anions]

SECTION 16 - ADDITIONAL INFORMATION
N/A