33820-53-0 (异乐灵,Isopropalin)

结构式:
CAS号:
33820-53-0
中文名称:
异乐灵
英文名称:
Isopropalin
安全信息:
分子式:
C15H23N3O4
分子量:
309.360823869705

异乐灵(33820-53-0)名称与标识符

名称

中文别名:
异乐灵;二氯吡啶酸酯乙酸酯;异丙乐灵;异丙乐灵 标准品;异东灵,二氯吡啶酸酯乙酸酯;异乐灵,Isopropalin ,分析标准品;4-异丙基-2,6-二硝基-N,N-二丙基苯胺;
英文别名:
Benzenamine,4-(1-methylethyl)-2,6-dinitro-N,N-dipropyl-;2,6-dinitro-4-propan-2-yl-N,N-dipropylaniline;Isopropalin;Isopropalin Solution;2,6-dinitro-4-(propan-2-yl)-N,N-dipropylaniline;2,6-dinitro-N,N-dipropylcumidine;4-(1-methylethyl)-2,6-dinitro-N,N-dipropylbenzenamine;4-isopropyl-2,6-dinitro-N,N-dipropylaniline;Caswell No. 506A;Isopropaline;N,n-di-n-propyl-4-isopropyl-2,6-dinitroaniline;Paarlan;EL 179;Aniline, 2,6-dinitro-N,N-dipropyl-p-isopropyl-;CHEBI:82189;Isopropalin, PESTANAL(R), analytical standard;Tox21_300422;NCGC00259777-01;AKOS015892015;4-isopropyl-2,6-dinitro-N,N-dipropyl-aniline;EL-179;UNII-52GZD1I41N;SCHEMBL55296;BRN 2762577;33820-53-0;J-019332;ISOPROPALIN [ISO];Cumidine, 2,6-dinitro-N,N-dipropyl-;(4-isopropyl-2,6-dinitrophenyl)dipropylamine;HSDB 6687;DTXSID8024157;Isopropaline [ISO-French];Isopropalin, analytical standard;EINECS 251-690-7;NCGC00254366-01;NCGC00248025-01;CAS-33820-53-0;NS00003426;ISOPROPALIN [MI];NEKOXWSIMFDGMA-UHFFFAOYSA-N;DTXCID904157;Isopropalin [ANSI:BSI:ISO];Q27155794;N-(4-Isopropyl-2,6-dinitrophenyl)-N,N-dipropylamine #;Benzenamine, 4-(1-methylethyl)-2,6-dinitro-N,N-dipropyl-;CHEMBL1256728;Tox21_202228;NCGC00248025-02;2,6-Dinitro-N,N-dipropyl-4-isopropylaniline;C19063;52GZD1I41N;EPA Pesticide Chemical Code 100201;ISOPROPALIN [HSDB];Benzenamine, 4(1methylethyl)2,6dinitroN,Ndipropyl (9CI);Benzenamine, 4(1methylethyl)2,6dinitroN,Ndipropyl;Isopropaline (ISO-French);Isopropalin (ANSI:BSI:ISO);EL179;4Isopropyl2,6dinitroN,Ndipropylaniline;Cumidine, 2,6dinitroN,Ndipropyl;2,6DinitroN,Ndipropylcumidine;4(1Methylethyl)2,6dinitroN,Ndipropylbenzenamine;2,6DinitroN,Ndipropyl4isopropylaniline;

标识符

MDL:
MFCD00055306
InChIKey:
NEKOXWSIMFDGMA-UHFFFAOYSA-N
Inchi:
1S/C15H23N3O4/c1-5-7-16(8-6-2)15-13(17(19)20)9-12(11(3)4)10-14(15)18(21)22/h9-11H,5-8H2,1-4H3
SMILES:
[O-][N+](C1C=C(C=C(C=1N(CCC)CCC)[N+](=O)[O-])C(C)C)=O

异乐灵(33820-53-0)物化性质

实验特性

  • LogP : 5.29920
  • PSA : 94.88000
  • 折射率 : 1.5600 (estimate)
  • 沸点 : 449.64°C (rough estimate)
  • 闪点 : 华氏:104 °F
    摄氏:40 °C
  • 溶解度 : Insuluble (2.2E-4 g/L) (25 ºC),
  • 颜色与性状 : 未确定
  • 溶解性 : 未确定
  • 密度 : 1.157±0.06 g/cm3 (20 ºC 760 Torr),

计算特性

  • 精确分子量 : 309.16900
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 8
  • 同位素质量 : 309.169
  • 重原子数量 : 22
  • 复杂度 : 348
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 94.9A^2

异乐灵(33820-53-0)安全信息

异乐灵(33820-53-0)国际标准相关数据

EINECS:
251-690-7

异乐灵(33820-53-0)海关数据

海关编码:
2921499011
海关数据:

中国海关编码:

2921499011

概述:

2921499011 异丙乐灵。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

Summary:

2921499011 4-isopropyl-2,6-dinitro-n,n-dipropylaniline。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

异乐灵(33820-53-0)生产方法和用途

用途:
异丙乐灵(33820-53-0)的作用方式: 试验用作植前拌土的选择除草剂。防治对象: 一年生禾本科杂草和某些阔叶杂草。适用作物: 移栽烟草、番茄和辣椒等茄科作物,高粱、燕麦、甜菜、菠菜等对本剂敏感,不可使用。

异乐灵(33820-53-0)推荐厂家 更多厂家(7)

公司名称手机号/电话联系人QQ微信询单
赫澎(上海)生物科技有限公司 13122891558
186-16545970
张硕 3418426269
询单
上海依赫生物科技有限公司 17721395025
021-68882955
张经理 2423903095
询单
金锦乐(湖南)化学有限公司 金锦乐 1226360695
询单
上海一基实业有限公司 13311756052
021-60526763 13311756052 13311756131
胡经理 2355265332
询单
深圳爱拓化学有限公司 13417589054肖小姐 2644020535 询单
上海源叶生物科技有限公司 15026964105
15026964105
汤思磊 2881489226
询单
上海源叶生物科技有限公司 15026964105
15026964105
汤思磊 2881489226
询单

异乐灵(33820-53-0)参考资料

Reaxys RN:
Beilstein:
2762577
PubChem CID:

异乐灵(33820-53-0) MSDS

基础信息


Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
  Product identifiers
    Product name        : Isopropalin    
    CAS-No.        : 33820-53-0    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    
  
  

Section 2. HAZARDS IDENTIFICATION
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
    Flammable liquids (Category 3)
    Acute aquatic toxicity (Category 1)
    Chronic aquatic toxicity (Category 1)
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    Flammable. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
    environment.
  Label elements
  Labelling according Regulation (EC) No 1272/2008 [CLP]
    Pictogram
    Signal word        Warning    
    Hazard statement(s)
    H226        Flammable liquid and vapour.    
    H410        Very toxic to aquatic life with long lasting effects.    
    Precautionary statement(s)
    P273        Avoid release to the environment.    
    P501        Dispose of contents/ container to an approved waste disposal plant.    
    Supplemental Hazard        none    
    Statements
  According to European Directive 67/548/EEC as amended.
    Hazard symbol(s)
    R-phrase(s)
    R10        Flammable.    
    R50/53        Very toxic to aquatic organisms, may cause long-term adverse effects in    
    the aquatic environment.
    S-phrase(s)
    S60        This material and its container must be disposed of as hazardous waste.    
    S61        Avoid release to the environment. Refer to special instructions/ Safety    
    data sheets.
  Other hazards - none

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substances
    Formula        : C15H23N3O4    
    Molecular Weight        : 309,36 g/mol    
    Component        Concentration    
  Isopropalin
    CAS-No.        33820-53-0        -    
    EC-No.        251-690-7    

Section 4. FIRST AID MEASURES
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
  In case of eye contact
    Flush eyes with water as a precaution.
  If swallowed
    Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with
    water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    To the best of our knowledge, the chemical, physical, and toxicological properties have not been
    thoroughly investigated.
  Indication of any immediate medical attention and special treatment needed
    no data available

Section 5. FIREFIGHTING MEASURES
  Extinguishing media
  Suitable extinguishing media
    For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large
    fires, apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or
    spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of
    water.
  Special hazards arising from the substance or mixture
    Carbon oxides, nitrogen oxides (NOx)
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    Use water spray to cool unopened containers.

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
    Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations.
    Vapours can accumulate in low areas.
  Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
    environment must be avoided.
  Methods and materials for containment and cleaning up
    Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and
    place in container for disposal according to local regulations (see section 13).
  Reference to other sections
    For disposal see section 13.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Avoid inhalation of vapour or mist.
    Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic
    charge.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage.
    Recommended storage temperature: 2 - 8 °C
  Specific end uses
    no data available

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
    at the end of workday.
  Personal protective equipment
  Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and approved under
    appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
  Body Protection
    impervious clothing, Flame retardant antistatic protective clothing, The type of protective
    equipment must be selected according to the concentration and amount of the dangerous
    substance at the specific workplace.
  Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator
    with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup
    to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
    respirator. Use respirators and components tested and approved under appropriate government
    standards such as NIOSH (US) or CEN (EU).

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Information on basic physical and chemical properties
    a) Appearance        Form: clear, liquid    
    Colour: dark red
    b) Odour        no data available    
    c) Odour Threshold        no data available    
    d) pH        no data available    
    e) Melting point/freezing        no data available    
    point
    f) Initial boiling point and no data available
    boiling range
    g) Flash point        40 °C    
    h) Evaporation rate        no data available    
    i) Flammability (solid, gas) no data available
    j) Upper/lower        no data available    
    flammability or
    explosive limits
    k) Vapour pressure        no data available    
    l) Vapour density        no data available    
    m) Relative density        no data available    
    n) Water solubility        no data available    
    o) Partition coefficient: n- log Pow: 4,690
    octanol/water
    p) Autoignition        no data available    
    temperature
    q) Decomposition        no data available    
    temperature
    r) Viscosity        no data available    
    s) Explosive properties        no data available    
    t) Oxidizing properties        no data available    
  Other safety information
    no data available

Section 10. STABILITY AND REACTIVITY
  Reactivity
    no data available
  Chemical stability
    no data available
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    Heat, flames and sparks.
  Incompatible materials
    Strong oxidizing agents
  Hazardous decomposition products
    Other decomposition products - no data available

Section 11. TOXICOLOGICAL INFORMATION
  Information on toxicological effects
  Acute toxicity
    LD50 Oral - rat - 5.000 mg/kg
    LD50 Dermal - rabbit - > 2.000 mg/kg
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
    no data available
  Respiratory or skin sensitization
    no data available
  Germ cell mutagenicity
    no data available
  Carcinogenicity
    IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as    
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    no data available
  Specific target organ toxicity - single exposure
    no data available
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    no data available
  Potential health effects
  Inhalation        May be harmful if inhaled. May cause respiratory tract irritation.    
  Ingestion        May be harmful if swallowed.    
  Skin        May be harmful if absorbed through skin. May cause skin irritation.    
  Eyes        May cause eye irritation.    
  Signs and Symptoms of Exposure
    To the best of our knowledge, the chemical, physical, and toxicological properties have not been
    thoroughly investigated.
  Additional Information
    RTECS: BX9286000

Section 12. ECOLOGICAL INFORMATION
  Toxicity
    Toxicity to fish        LC50 - Pimephales promelas (fathead minnow) - 0,27 mg/l - 96,0 h    
    Toxicity to daphnia and        mortality EC50 - Daphnia magna (Water flea) - 0,03 mg/l - 48 h    
    other aquatic
    invertebrates
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    no data available
  Other adverse effects
    Very toxic to aquatic life with long lasting effects.

Section 13. DISPOSAL CONSIDERATIONS
  Waste treatment methods
  Product
    Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting
    as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal
    company. Contact a licensed professional waste disposal service to dispose of this material.
  Contaminated packaging
    Dispose of as unused product.

Section 14. TRANSPORT INFORMATION
  UN number
    ADR/RID: 1993        IMDG: 1993        IATA: 1993    
  UN proper shipping name
    ADR/RID: FLAMMABLE LIQUID, N.O.S. (Isopropalin)
    IMDG: FLAMMABLE LIQUID, N.O.S. (Isopropalin)
    IATA:        Flammable liquid, n.o.s. (Isopropalin)    
  Transport hazard class(es)
    ADR/RID: 3        IMDG: 3        IATA: 3    
  Packaging group
    ADR/RID: III        IMDG: III        IATA: III    
  Environmental hazards
    ADR/RID: no        IMDG Marine pollutant: no        IATA: no    
  Special precautions for user
    no data available



SECTION 15 - REGULATORY INFORMATION
N/A


SECTION 16 - ADDITIONAL INFORMATION
N/A