3401-47-6 (1-溴-2-甲氧基萘,1-Bromo-2-methoxy-naphthalene)

快速询单

结构式：

1-溴-2-甲氧基萘MOL文件

CAS号：

3401-47-6

中文名称：

1-溴-2-甲氧基萘

英文名称：

1-Bromo-2-methoxy-naphthalene

分子式：

C₁₁H₉BrO

分子量：

237.092562437057

1-溴-2-甲氧基萘(3401-47-6)名称与标识符

名称

中文别名：

1-溴-2-甲氧基萘;1-溴-2-萘甲醚;11a-羟基-16,17a-环氧孕酮;

英文别名：

1-Bromo-2-methoxynaphthalene;1-Bromo-2-methoxy-naphthalene;1-bromo-2-methoxynaphtalene;2-methoxy-1-bromonaphthalene;2-methoxylnaphthyl bromide;bromo-2-methoxynaphthalene;Naphthalene,1-bromo-2-methoxy;1-Bromo-2-methoxy-naphtalene;AM20040214;MFCD00055374;HMS1445J08;FT-0634835;B6103;Naphthalene, 1-bromo-2-methoxy-;IDI1_016521;2-Methoxy-1-naphtyl bromide;AE-848/30709025;3401-47-6;AKOS005203358;NSC110660;SR-01000640482-1;NSC 110660;DS-14878;A18667;SCHEMBL617210;NSC-110660;CS-W004988;J-019420;CCG-51167;EINECS 222-272-1;NS00029596;SY037749;DTXSID40187622;EN300-249583;Maybridge3_005134;DB-019065;DTXCID00110113;

标识符

MDL：

MFCD00055374

InChIKey：

XNIGURFWNPLWJM-UHFFFAOYSA-N

Inchi：

1S/C11H9BrO/c1-13-10-7-6-8-4-2-3-5-9(8)11(10)12/h2-7H,1H3

SMILES：

BrC1C(=CC=C2C=CC=CC2=1)OC

BRN：

2045600

1-溴-2-甲氧基萘(3401-47-6)物化性质

实验特性

LogP : 3.61090
PSA : 9.23000
折射率 : 1.632
水溶性 : Slightly soluble in water.
沸点 : 319.2℃ at 760 mmHg
熔点 : 80-83 ºC
蒸气压 : 0.0±0.7 mmHg at 25°C
闪点 : 132.9 ºC
颜色与性状 : 粉末
溶解性 : 未确定
密度 : 1.447

计算特性

精确分子量 : 235.98400
氢键供体数量 : 0
氢键受体数量 : 1
可旋转化学键数量 : 1
同位素质量 : 235.984
重原子数量 : 13
复杂度 : 172
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 3.8
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 9.2A^2

1-溴-2-甲氧基萘(3401-47-6)安全信息

WGK Germany： 3
安全说明： S26-S36
风险术语： R36/37/38
危险品标志： Xi
危害声明：H315+H319
警示性声明：P264+P280+P302+P352+P332+P313+P362+P364+P305+P351+P338+P337+P313
储存条件： 4℃条件下存储,-4℃存储更佳
危险类别码： R36/37/38
信号词：警告

1-溴-2-甲氧基萘(3401-47-6)国际标准相关数据

EINECS：

222-272-1

1-溴-2-甲氧基萘(3401-47-6)海关数据

海关编码：

2909309090

海关数据：

中国海关编码：

2909309090

概述：

2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

申报要素：

品名, 成分含量, 用途

Summary：

2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

1-溴-2-甲氧基萘(3401-47-6)推荐厂家更多厂家(52)

公司名称	手机号/电话	联系人	QQ	询单
湖北成海化工有限公司	13986212397 027-59220433	张思胧	1400858822	询单
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上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
湖北摆渡化学有限公司	13517219350 13517219350	彭星	1400878899	询单
郑州阿尔法化工有限公司	15324716602 0371-55013243	刘经理	2853979810	询单
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湖北广奥生物科技有限公司	13657291602 13657291602	郭银	1098480033	询单
上海绩祥生物科技有限公司	13093077543	陆经理	3985448220	询单
湖北永阔科技有限公司	18771920143 027-59223108	郭经理	1248580055	询单

1-溴-2-甲氧基萘(3401-47-6)上下游

(S)-(+)-2-氨基-2'-羟基-1,1'-联萘 (S)-(-)-1-(2-二苯基膦-1-萘)异喹啉 S-联萘酚 (R)-(+)-2,2'-二甲氧基-1,1'-联萘 (S)-(-)-2,2'-二甲氧基-1,1'-联萘 2-乙酰-5-溴-6-甲氧基萘

1-溴-2-甲氧基萘(3401-47-6)相关文献

1. A comparison of MOP-phosphonite ligands and their applications in Rh(i)- and Pd(ii)-catalysed asymmetric transformations
James T. Fleming,Corinne Wills,Paul G. Waddell,Ross W. Harrington,Lee J. Higham Dalton Trans. 2016 45 15660
2. 123. Methoxylated o-benzoylbenzoic acids
Ch. Weizmann,Ernst Bergmann J. Chem. Soc. 1936 567
3. Self-condensation of 1-bromo-2-naphthol: mechanism of formation of a 1,4-dinaphthodioxin
Luciano Forlani,Andrea Lugli,Daniele Nanni,Paolo E. Todesco J. Chem. Soc. Perkin Trans. 2 1994 1291
4. Solid-state structure, solution-state behaviour and catalytic activity of electronically divergent C,N-chelating palladium–N-heterocyclic carbene complexes
Michael R. Chapman,Benjamin R. M. Lake,Christopher M. Pask,Bao N. Nguyen,Charlotte E. Willans Dalton Trans. 2015 44 15938
5. Synthesis of a class of binaphthyl monophosphine ligands with a naphthofuran skeleton and their applications in Suzuki–Miyaura coupling reactions
Zihong Zhou,Hao Liang,Wang Xia,Huixuan Chen,Yaqi Zhang,Xuefeng He,Sifan Yu,Rihui Cao,Liqin Qiu New J. Chem. 2018 42 5967
6. Two-in-one strategy for fluorene-based spirocycles via Pd(0)-catalyzed spiroannulation of o-iodobiaryls with bromonaphthols
Bojun Tan,Long Liu,Huayu Zheng,Tianyi Cheng,Dianhu Zhu,Xiaofeng Yang,Xinjun Luan Chem. Sci. 2020 11 10198
7. 1,3-Benzodioxole-2-spirocyclohexadien-4′-one and some of its derivatives
I. G. C. Coutts,D. J. Humphreys,K. Schofield J. Chem. Soc. C 1969 1982
8. Amino acid-derived bisphenolate palladium complexes as C–C coupling catalysts
Eszter Fazekas,David T. Jenkins,Andrew A. Forbes,Brendan Gallagher,Georgina M. Rosair,Ruaraidh D. McIntosh Dalton Trans. 2021 50 17625
9. Note
Frank L Warren,Munir Gindy,Fawzy Ghali Baddar J. Chem. Soc. 1941 687
10. Pd/tetraphosphine catalytic system for Cu-free Sonogashira reaction “on water”
Rong Zhou,Wei Wang,Zhi-jie Jiang,Hai-yan Fu,Xue-li Zheng,Chun-chun Zhang,Hua Chen,Rui-xiang Li Catal. Sci. Technol. 2014 4 746

1-溴-2-甲氧基萘(3401-47-6)参考资料

Reaxys RN：

PubChem CID：

72860

1-溴-2-甲氧基萘(3401-47-6) MSDS

基础信息

Material Safety Data Sheet

Section 1. Identi?cation of the substance
Product Name: 1-Bromo-2-methoxynaphthalene
Synonyms:

Section 2. Hazards identi?cation
Harmful by inhalation, in contact with skin, and if swallowed.

Section 3. Composition/information on ingredients.
Ingredient name: 1-Bromo-2-methoxynaphthalene
CAS number: 3401-47-6

Section 4. First aid measures
    Skin contact:        Immediately wash skin with copious amounts of water for at least 15 minutes while removing
    contaminated clothing and shoes. If irritation persists, seek medical attention.
    Eye contact:        Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
    ?ushing of the eyes by separating the eyelids with ?ngers. If irritation persists, seek medical
    attention.
    Inhalation:        Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
    Ingestion:        Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section 5. Fire ?ghting measures
    In the event of a ?re involving this material, alone or in combination with other materials, use dry
    powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
    should be worn.

Section 6. Accidental release measures
    Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
    standards.
    Respiratory precaution:        Wear approved mask/respirator
    Hand precaution:        Wear suitable gloves/gauntlets
    Skin protection:        Wear suitable protective clothing
    Eye protection:        Wear suitable eye protection
    Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
    for disposal. See section 12.
    Environmental precautions: Do not allow material to enter drains or water courses.

Section 7. Handling and storage
    Handling:        This product should be handled only by, or under the close supervision of, those properly quali?ed
    in the handling and use of potentially hazardous chemicals, who should take into account the ?re,
    health and chemical hazard data given on this sheet.
    Store in closed vessels.
    Storage:

Section 8. Exposure Controls / Personal protection
    Engineering Controls: Use only in a chemical fume hood.
    Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
    General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. Physical and chemical properties
    Appearance:        Not speci?ed
    Boiling point:        No data
    No data
    Melting point:
    Flash point:        No data
    Density:        No data
    Molecular formula:        C11H9BrO
    Molecular weight:        237.1

Section 10. Stability and reactivity
    Conditions to avoid: Heat, ?ames and sparks.
    Materials to avoid: Oxidizing agents.
    Possible hazardous combustion products: Carbon monoxide, hydrogen bromide.

Section 11. Toxicological information
No data.

Section 12. Ecological information
No data.

Section 13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section 14. Transportation information
Non-harzardous for air and ground transportation.

Section 15. Regulatory information
    No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
    302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
    Title III, Section 313.

SECTION 16 - ADDITIONAL INFORMATION
N/A