3426-89-9 (二氯亚磷酸苯酯,Phenylphosphorodichloridite)

CAS号:
3426-89-9
中文名称:
二氯亚磷酸苯酯
英文名称:
Phenylphosphorodichloridite
分子式:
C6H5Cl2OP
分子量:
194.983060598373

二氯亚磷酸苯酯(3426-89-9)名称与标识符

名称

中文别名:
苯氧基亚磷酰二氯;二氯亚磷酸苯酯;
英文别名:
Phosphorodichloridousacid, phenyl ester;dichloro(phenoxy)phosphane;PHENYL PHOSPHORODICHLORIDITE;diacid chloride of phenyl phosphorous acid;Dichlorophenoxyphosphine;EINECS 222-330-6;Phenoxyphosphorus dichloride;phenyl dichlorophosphinite;Phenyl dichlorophosphite;phenyl phosphorodichloridate;Phenyl-phosphorodichloridit;Phosphorigsaeurephenylesterdichlorid;phosphorodichloridite of phenol;MFCD00041721;Phosphorodichloridous acid phenyl ester;DTXSID5063021;SCHEMBL991332;Phenyl dichloridophosphite #;Phenylphosphoro dichloridite;PHOSPHORODICHLORIDOUS ACID, PHENYL ESTER;NS00048850;BRN 1866404;3426-89-9;4-06-00-00701 (Beilstein Handbook Reference);dichloro(phenoxy)phosphine;FT-0693838;

标识符

InChIKey:
LXHWDUISRBUGRA-UHFFFAOYSA-N
Inchi:
1S/C6H5Cl2OP/c7-10(8)9-6-4-2-1-3-5-6/h1-5H
SMILES:
ClP(OC1C=CC=CC=1)Cl

二氯亚磷酸苯酯(3426-89-9)物化性质

实验特性

  • LogP : 3.76990
  • PSA : 22.82000
  • 沸点 : 99 °C (12 mmHg)
  • 颜色与性状 : 无色透明液体
  • 溶解性 : 溶于大多数非质子有机溶剂。
  • 密度 : 1.359

计算特性

  • 精确分子量 : 193.94600
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 1
  • 同位素质量 : 193.9455072g/mol
  • 重原子数量 : 10
  • 复杂度 : 93.7
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 3.4
  • 互变异构体数量 : 2
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 9.2

二氯亚磷酸苯酯(3426-89-9)安全信息

二氯亚磷酸苯酯(3426-89-9)海关数据

海关编码:
2909309090
海关数据:

中国海关编码:

2909309090

概述:

2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物(包括亚硝化衍生物)。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

二氯亚磷酸苯酯(3426-89-9)推荐厂家 更多厂家(1)

公司名称手机号/电话联系人QQ微信询单
金锦乐(湖南)化学有限公司 金锦乐 1226360695
询单

二氯亚磷酸苯酯(3426-89-9)上下游

二氯亚磷酸苯酯(3426-89-9) MSDS

基础信息

Name:Phenyl Phosphorodichloridite Material Safety Data Sheet
Synonym:Phosphorodichloridous Acid, Phenyl Ester; Dichlorophenoxyphosphine
CAS:3426-89-9
Section 1 - Chemical Product ? MSDS Name:Phenyl Phosphorodichloridite Material Safety Data Sheet
Synonym:Phosphorodichloridous Acid, Phenyl Ester; Dichlorophenoxyphosphine

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
3426-89-9Phosphorodichloridous Acid, Phenyl Estca 100222-330-6
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 3426-89-9: Personal Protective Equipment Eyes: Wear chemical splash goggles. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Liquid
Color: clear colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 99 deg C @ 12.00mm Hg
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3590g/cm3
Molecular Formula: C6H5Cl2OP
Molecular Weight: 194.98

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Not available.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 3426-89-9: TD4440000 LD50/LC50:
CAS# 3426-89-9: Inhalation, rat: LC50 = >2080 mg/m3/1H; Oral, rat: LD50 = 681 mg/kg.
Carcinogenicity:
Phosphorodichloridous Acid, Phenyl Ester - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 3426-89-9: No information available.
Canada
CAS# 3426-89-9 is listed on Canada's NDSL List.
CAS# 3426-89-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3426-89-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A