484-11-7 (新铜试剂,Neocuproine)

CAS号:
484-11-7
中文名称:
新铜试剂
英文名称:
Neocuproine
分子式:
C14H12N2
分子量:
208.258482933044
简介:
一种用于铜测定的试剂,白色或黄褐色结晶。易溶于乙醇、正戊醇、异戊醇、正己醇、氯仿和苯,微溶于冷水。有刺激性。

新铜试剂(484-11-7)名称与标识符

名称

中文别名:
新铜试剂;2,9-二甲基-1,10-菲罗啉;2,9-二甲基-1,10-菲啰啉(新铜试剂);2,9-二甲基-1,10-非啰啉;2,9-二甲基-1,10-菲咯啉;2,9-二甲基-1,10-菲啰啉;2,9二甲基-1,10-菲啰啉;尼尔古博试剂;新铜试剂(2,9-二甲基-1,10-菲罗啉);新铜试剂(2.9-二甲基邻非罗林);新铜试剂(2.9-二甲基邻非罗林),AR;新铜试剂(2.9-二甲基邻非罗林),进分;新亚铜试剂;新亚铜试剂半水合物;2,9-二甲基-1,10-菲罗啉,新铜试剂,2,9-二甲基-1,10-邻菲罗啉,新亚铜试剂 水合物;2,9-二甲基-1,10-邻菲咯啉;2,9-二甲基-1,10-邻菲罗啉;2,9-二甲基-1,10-邻菲洛啉;2,9-二甲基邻菲啰啉;2.9-二甲基-1.10-菲罗啉;9-二甲基-1,10-邻菲洛啉;Me2一phen;双环已酮草酰二腙;双喹哪啶;新铜试剂,半水;
英文别名:
2,9-Dimethyl-1,10-phenanthroline;2,9-Dimethyl-1,10-phenanthroline hemihydrate;Neocuproine hemihydrate;neocuproine free base;2,9-DIMETHYL-1,10-PHENANT;Neocuproine;NEOCUPROINE GR;NEOCUPROINE(RG);Neocupro-ine;DMPHEN;Neocuproin;1,10-Phenanthroline, 2,9-dimethyl-;2,9-Dimethylphenanthroline;2,9-Dimethyl-o-phenanthroline;neo-Cuproin;NSC4280;8E7D2SH3BV;MLS001194484;IYRGXJIJGHOCFS-UHFFFAOYSA-N;SMR000555011;2,9-dimethylpyridino[3,2-h]quinoline;neocuproine monohydrochloride;3,6-dimethyl-4,5-phenanthroline;2,10-phenanthroline;Neocuproine, >=98%;1, 2,9-d;34302-69-7;EINECS 207-601-9;DNDI1343110;CHEMBL375781;EU-0036872;2,9-Dimethyl-1,10-phenanthroline Neocuproine;A827529;HMS2230M06;CS-W004563;NEOCUPROINE [MI];MFCD00149306;2,9-NEOCUPROINE;MEPHEN;SCHEMBL124563;3,6-Dimethyl-4,5-diazaphenanthrene;NS00005029;Z1224384937;BDBM64740;SY010909;NCI60_003986;cid_65237;Q409347;NSC-4280;Oprea1_068014;484-11-7 (anhydrous);EN300-196274;UNII-8E7D2SH3BV;1, 2,9-dimethyl-;HMS3373K19;VUF-7738;2,9-di-methyl-1,10-phenanthroline;AS-14894;NCGC00245843-01;FT-0610770;F20419;AKOS000511700;AB00443806-12;AB00443806-10;KUC107774N;MFCD00004973;GNF-PF-5611;484-11-7;D0771;J-610070;BCP18357;2,9-Dimethyl-1,10-phenanthroline hemihydrate, 98%;NCIMech_000034;Neocuproine, Vetec(TM) reagent grade, 98%;CHEBI:91222;BRD-K16598630-001-05-7;DTXSID5060065;CCG-35468;CCG-16034;KSC-09-264B;HY-W004563;DMPHEN; NSC 4280; Neocuproin; VUF 7738;NSC 4280;doi:10.14272/IYRGXJIJGHOCFS-UHFFFAOYSA-N.1;2,9Dimethylophenanthroline;DB-050426;2,9-dimethyl[1,10]phenanthroline;2,9dimethylphenanthroline;DTXCID1040619;AG-690/12868020;2,9Dimethyl1,10phenanthroline;1,10Phenanthroline, 2,9dimethyl;230-732-8;FD32093;

标识符

MDL:
MFCD00004973
InChIKey:
IYRGXJIJGHOCFS-UHFFFAOYSA-N
Inchi:
1S/C14H12N2/c1-9-3-5-11-7-8-12-6-4-10(2)16-14(12)13(11)15-9/h3-8H,1-2H3
SMILES:
N1C(C)=CC=C2C=CC3=CC=C(C)N=C3C=12

新铜试剂(484-11-7)物化性质

实验特性

  • LogP : 3.39980
  • PSA : 25.78000
  • Merck : 6449
  • 折射率 : 1.6152 (estimate)
  • 水溶性 : 微溶
  • 沸点 : 337.46°C (rough estimate)
  • 熔点 : 158-163 ºC
  • 闪点 : 159.7 °C
  • 溶解度 : methanol: 0.1 g/mL, clear
  • 颜色与性状 : 未确定
  • 溶解性 : 微溶于水
  • 敏感性 : Light Sensitive
  • 密度 : 1.1345 (rough estimate)

计算特性

  • 精确分子量 : 208.10000
  • 氢键供体数量 : 0
  • 氢键受体数量 : 2
  • 可旋转化学键数量 : 0
  • 同位素质量 : 208.1
  • 重原子数量 : 16
  • 复杂度 : 227
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 3.3
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 25.8

新铜试剂(484-11-7)国际标准相关数据

EINECS:
4280

新铜试剂(484-11-7)海关数据

海关编码:
29339990
海关数据:

中国海关编码:

2933990090

概述:

2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素:

品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期

Summary:

2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

新铜试剂(484-11-7)生产方法和用途

用途:
光度分析测定铜,测定超微血糖。有机合成。
生产方法:
暂无

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新铜试剂(484-11-7)相关文献

新铜试剂(484-11-7) MSDS

基础信息

Name:2 9-Dimethyl-1 10-phenanthroline Material Safety Data Sheet
Synonym:Neocuproine hemihydrat
CAS:484-11-7
Section 1 - Chemical Product ? MSDS Name:2 9-Dimethyl-1 10-phenanthroline Material Safety Data Sheet
Synonym:Neocuproine hemihydrat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
484-11-72,9-Dimethyl-1,10-phenanthroline100207-601-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Light sensitive.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Store protected from light.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 484-11-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 160 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C14H12N2.0.5H2O
Molecular Weight: 225.1038

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 484-11-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,9-Dimethyl-1,10-phenanthroline - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 484-11-7: 1
Canada
CAS# 484-11-7 is listed on Canada's DSL List.
CAS# 484-11-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 484-11-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A