488-48-2 (对四溴苯醌,Bromanil)

快速询单

结构式：

对四溴苯醌MOL文件

CAS号：

488-48-2

中文名称：

对四溴苯醌

英文名称：

Bromanil

安全信息：

分子式：

C₆Br₄O₂

分子量：

423.678998947144

简介：

对四溴苯醌，化学式C6Br4O2，分子量424，有机化合物。

对四溴苯醌(488-48-2)名称与标识符

名称

中文别名：

对四溴苯醌;四溴-1,4-苯醌;四溴对苯醌;Bromanil 四溴对苯醌;四溴-p-苯醌;金莲橙O;四溴苯醌;

英文别名：

2,3,5,6-Tetrabromocyclohexa-2,5-diene-1,4-dione;Bromanil;Tetrabromo-1,4-benzoquinone;2,3,5,6-TETRABROMO-(1,4)BENZOQUINONE;Q312 TETRABROMO-1,4-BENZOQUINONE;Tetrabromo-p-benzoquinone;Tropaeolin O;2,3,5,6-tetrabromo-p-benzoquinon;2,3,5,6-tetrabromo-p-benzoquinone;4-dione, 2,3,5,6-tetrabromo-5-cyclohexadiene-1;Tetrabromoquinone;p-Bromanil;p-Bromoanil;Bromanyl;Tetrabromo-p-quinone;Tetrabromobenzoquinone;p-Quinone, tetrabromo-;2,3,5,6-Tetrabromo-1,4-benzoquinone;p-Benzoquinone, tetrabromo-;p-Benzoquinone, 2,3,5,6-tetrabromo-;2,5-Cyclohexadiene-1,4-dione, 2,3,5,6-tetrabromo-;LWHDQPLUIFIFFT-UHFFFAOYSA-N;Tetrabromo-p-benzoquinon;D92370;DTXSID20197608;SCHEMBL638801;T0617;NSC-36927;p-Benzoquinone,3,5,6-tetrabromo-;2,3,5,6-Tetrabromobenzo-1,4-quinone #;NSC36927;A871873;MFCD00013785;AKOS001030624;NSC 36927;tetrabromocyclohexa-2,5-diene-1,4-dione;Tetrabromobenzo-1,4-quinone;AKOS025243337;FT-0623203;CS-W009681;2,5,6-Tetrabromo-1,4-benzoquinone;488-48-2;2,5,6-Tetrabromo-p-benzoquinone;AS-18102;EINECS 207-679-4;NS00031829;2,4-dione, 2,3,5,6-tetrabromo-;STL557868;DB-051582;BBL104054;

标识符

MDL：

MFCD00013785

InChIKey：

LWHDQPLUIFIFFT-UHFFFAOYSA-N

Inchi：

1S/C6Br4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11

SMILES：

BrC1C(C(=C(C(C=1Br)=O)Br)Br)=O

BRN：

1912183

对四溴苯醌(488-48-2)物化性质

实验特性

LogP : 3.14100
PSA : 34.14000
折射率 : 1.806
沸点 : 340.5±42.0 ºC (760 Torr),
熔点 : 303-304 ºC
闪点 : 120.0±14.4 ºC,
溶解度 : 几乎不溶 (0.047 g/L) (25 ºC),
颜色与性状 : 未确定
溶解性 : 未确定
敏感性 : 对光敏感
密度 : 3.127±0.06 g/cm3 (20 ºC 760 Torr),

计算特性

精确分子量 : 419.66300
氢键供体数量 : 0
氢键受体数量 : 2
可旋转化学键数量 : 0
同位素质量 : 419.66318
重原子数量 : 12
复杂度 : 278
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 3.6
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 34.1

对四溴苯醌(488-48-2)安全信息

符号： GHS07
RTECS号： DK6772500
WGK Germany： 3
安全说明： S26-S37/39
风险术语： R36/37/38
危险品标志： Xi
危害声明：H315,H319,
警示性声明：P264,P280,P302+P350,P305+P351+P338,P332+P313,P337+P313,P362
提示语：警告
危险类别码： 36/37/38
信号词： Warning
HazardClass： IRRITANT

对四溴苯醌(488-48-2)国际标准相关数据

EINECS：

36927

对四溴苯醌(488-48-2)海关数据

海关编码：

2914700090

海关数据：

中国海关编码：

2914700090

概述：

2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 丙酮报明包装

Summary：

HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

对四溴苯醌(488-48-2)推荐厂家更多厂家(39)

公司名称	手机号/电话	联系人	QQ	询单
湖北永阔科技有限公司	18064098002 027-59223108	孙瑶	1248580055	询单
郑州阿尔法化工有限公司	15324716602 0371-55013243	刘经理	2853979810	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982	询单
江西伯业医药科技有限公司	15377010747 027-81625225	李端慧	3266171690	询单
西安德而塔生物科技有限公司	18133906270 18133906270	张女士	2590956145	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
上海绩祥生物科技有限公司	13093077543	陆经理	3985448220	询单
湖北拓邦化工有限公司	15102763473 027-59106185	涂梦婷	1400868822/1248089955	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单

对四溴苯醌(488-48-2)相关文献

1. Pd-catalyzed threefold arylations of mono, di and tetra-bromoquinones using triarylbismuth reagents
Maddali L. N. Rao,Somnath Giri RSC Adv. 2012 2 12739
2. Thiophene-benzoquinones: synthesis, crystal structures and preliminary coordination chemistry of derived anilate ligands
Matteo Atzori,Flavia Pop,Thomas Cauchy,Maria Laura Mercuri,Narcis Avarvari Org. Biomol. Chem. 2014 12 8752
3. Analytical uses of charge-transfer complexes: determination of pure and dosage forms of piperazine
U. Muralikrishna,Mannam Krishnamurthy,N. Someswara Rao Analyst 1984 109 1277
4. The factor which determines whether excitation of charge-transfer complexes leads to final net products in comparison with the reactivity on excitation of one of the components
Naoki Haga,Hiroaki Takayanagi,Katsumi Tokumaru Photochem. Photobiol. Sci. 2003 2 1215
5. Design, synthesis and cytotoxic activity of water-soluble quinones with dibromo-p-benzoquinone cores and amino oligo(ethylene glycol) side chains against MCF-7 breast cancer cells
Leon F. Scherz,Engy A. Abdel-Rahman,Sameh S. Ali,A. Dieter Schlüter,Mona A. Abdel-Rahman Med. Chem. Commun. 2017 8 662
6. Enhanced catalytic activity of oxovanadium complexes in oxidative polymerization of diphenyl disulfide
Fuyuki Aida,Yohei Takatori,Daichi Kiyokawa,Kentaro Nagamatsu,Kenichi Oyaizu,Hiroyuki Nishide Polym. Chem. 2016 7 2087
7. Discovery and properties of a new indigoid structure type based on dimeric cis-indigos
Hyejin Hong,Cassidy M. Conover,Dillon T. Hofsommer,Corey A. Sanz,Robin G. Hicks Org. Biomol. Chem. 2020 18 5838
8. Charge transfer interaction between tetrahalo p-benzoquinones and polynuclear aromatic hydrocarbons
Saroj Kumar Chakrabarti,Sadhan Basu Trans. Faraday Soc. 1964 60 465
9. Stabilisation of tetrabromo- and tetrachlorosemiquinone (bromanil and chloranil) anion radicals in crystals
Kre?imir Mol?anov,Biserka Koji?-Prodi?,Darko Babi?,Dijana ?ili?,Boris Rakvin CrystEngComm 2011 13 5170
10. Incipient spin–dipole coupling in a 1D helical-chain metal–organic hybrid
Tathamay Basu,Clarisse Bloyet,Jean-Michel Rueff,Vincent Caignaert,Alain Pautrat,Bernard Raveau,Guillaume Rogez,Paul-Alain Jaffrès J. Mater. Chem. C 2018 6 10207

对四溴苯醌(488-48-2)参考资料

Reaxys RN：

1912183

Beilstein：

7,604

PubChem CID：

87576510

对四溴苯醌(488-48-2) MSDS

基础信息

Bromanil Revision number: 5
SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Bromanil

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
  Skin corrosion/irritation        Category 2
    Category 2A
  Serious eye damage/eye irritation
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning
  Hazard statements        Causes skin irritation
    Causes serious eye irritation
  Precautionary statements:
    Wash hands thoroughly after handling.
  [Prevention]
    Wear protective gloves/eye protection/face protection.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
  [Response]
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Take off contaminated clothing and wash before reuse.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Components:        Bromanil
  Percent:        >98.0%(T)
  CAS Number:        488-48-2
  Synonyms:        Tetrabromo-1,4-benzoquinone
    C6Br4O2
  Chemical Formula:

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Bromanil

Section 4. FIRST AID MEASURES
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
    Safety glasses. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
    Crystal- Powder
  Form:
  Colour:        Yellow
    No data available
  Odour:
  Bromanil

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        No data available
  Flash point:        No data available
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        No data available
  Solubility(ies):
  [Water]        Insoluble
  [Other solvents]        No data available

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        ipr-mus LD:>500 mg/kg
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available
  Reproductive toxicity:        No data available
  RTECS Number:        DK6772500

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations
  UN-No:        Not listed
  Bromanil

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A