49669-14-9 (2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶,2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)pyridine)

快速询单

结构式：

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶MOL文件

CAS号：

49669-14-9

中文名称：

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶

英文名称：

2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)pyridine

分子式：

C₉H₁₀BrNO₂

分子量：

244.085201740265

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9)名称与标识符

名称

中文别名：

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶;2-溴-6-乙酰基吡啶乙二醇保护;2-溴-6-(2-甲基-1,3-二氧戊环-2-基)吡啶;2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)pyridine 2-溴-6-(2-甲基-1,3-二氧戊环-2-基)吡啶;2-溴-6-(2-甲基-1,3-二氧杂烷)吡啶;2-溴-6-乙酰基吡啶闭环;2-溴-6-乙酰基吡啶乙二醇;

英文别名：

2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)pyridine;RW1992;2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)-pyridine;Pyridine, 2-bromo-6-(2-methyl-1,3-dioxolan-2-yl)-;PubChem16082;KSC496I5P;ZRXWMMNBTGBCIL-UHFFFAOYSA-N;TRA0083464;FCH1345626;BC004070;SY021683;AX8212144;AB0006599;AB1008631;B4512;ST24040170;FT-;2-[(1,3-BENZOTHIAZOL-2-YLTHIO)METHYL]BENZOICACID;SCHEMBL876768;MFCD12406888;FT-0698476;A827788;AKOS015835789;DTXSID30478970;AS-11062;CS-0153767;49669-14-9;2-Bromo-6-(2-methyl-[1,3]dioxolan-2-yl)-pyridine;FT-0659380;AC-5078;

标识符

MDL：

MFCD12406888

InChIKey：

ZRXWMMNBTGBCIL-UHFFFAOYSA-N

Inchi：

1S/C9H10BrNO2/c1-9(12-5-6-13-9)7-3-2-4-8(10)11-7/h2-4H,5-6H2,1H3

SMILES：

BrC1=CC=CC(C2(C)OCCO2)=N1

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9)物化性质

实验特性

LogP : 2.06360
PSA : 31.35000
折射率 : 1.55
沸点 : 322.7℃ at 760 mmHg
熔点 : 43.0 to 47.0 deg-C
闪点 : 322.7 °C at 760 mmHg
密度 : 1.499

计算特性

精确分子量 : 242.98900
氢键供体数量 : 0
氢键受体数量 : 3
可旋转化学键数量 : 1
同位素质量 : 242.98949g/mol
重原子数量 : 13
复杂度 : 183
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 1.5
拓扑分子极性表面积 : 31.4

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9)安全信息

危害声明：H315; H319; H335
警示性声明：P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501
储存条件： Store at room temperature
信号词： Warning

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9)海关数据

海关编码：

2932999099

海关数据：

中国海关编码：

2932999099

概述：

2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素：

品名, 成分含量, 用途

Summary：

2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9)上下游

6-(2-甲基-1,3-二氧杂烷-2-基)-2-吡啶羧酸 6-乙酰基吡啶-2-羧酸乙二醇 2-溴-6-乙酰基吡啶 2,6-二溴吡啶

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9)相关文献

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2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9)参考资料

Reaxys RN：

1107363

PubChem CID：

253662127

2-溴-6-(2-甲基-1,3-二氧戊烷-2-基)吡啶(49669-14-9) MSDS

基础信息

2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)pyridine
SAFETY DATA SHEET

Section 1. IDENTIFICATION
Product name: 2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)pyridine
5.3

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified
    Not classified
  HEALTH HAZARDS
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols        None
    No signal word
  Signal word
  Hazard statements        None
    None
  Precautionary statements:

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Components:        2-Bromo-6-(2-methyl-1,3-dioxolan-2-yl)pyridine
  Percent:        >98.0%(GC)
  CAS Number:        49669-14-9
  Chemical Formula:        C9H10BrNO2

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.

Section 5. FIRE-FIGHTING MEASURES
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Handling is performed in a well ventilated place. Wear suitable protective equipment.
  Technical measures:
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
    Install a closed system or local exhaust as possible so that workers should not be
  Engineering controls:
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
  Form:        Crystal- Powder
  Colour:        Very pale yellow - Pale yellow
  Odour:        No data available
  pH: No data available
  Melting point/freezing point:45°C
    No data available
  Boiling point/range:
  Flash point:        No data available
  Flammability or explosive
  limits:
    No data available
  Lower:
  Upper:        No data available
    No data available
  Relative density:
  Solubility(ies):
    No data available
  [Water]
  [Other solvents]        No data available

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen bromide
  products:

Section 11. TOXICOLOGICAL INFORMATION
    No data available
  Acute Toxicity:
  Skin corrosion/irritation: No data available
    No data available
  Serious eye
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  NTP =        No data available
    No data available
  Reproductive toxicity:

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
    No data available
  Fish:
  Crustacea:        No data available
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
    No data available
  Soil adsorption (Koc):
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations
    Not listed
  UN-No:

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A