526-94-3 (酒石酸氢钠,Sodium bitartrate)

CAS号:
526-94-3
中文名称:
酒石酸氢钠
英文名称:
Sodium bitartrate
分子式:
C4H5NaO6
分子量:
172.0687

酒石酸氢钠(526-94-3)名称与标识符

名称

中文别名:
酒石酸氢钠;L-酒石酸氢钠;酒石酸氢钠单水合物;2,3-二羟基-[R-(R*,R*)]-丁二酸单钠盐;酒石酸氢钠(一水);酒石酸氢钠,一水;酒石酸氢钠单水合物,AR;酒石酸氢钠单水合物,CP;酒石酸氢钠一水合物;酒石酸氢钠,无水;酸性酒石酸钠;重酒石酸钠;重酒石酸钠,酸性酒石酸钠, 2,3-二羟基-[R-(R*,R*)]-丁二酸单钠盐,一水酒石酸氢钠;L(+)-酒石酸 单钠盐;酒石酸 单钠盐;
英文别名:
sodium hydrogen tartrate monohydrate;Sodium hydrogen L-tartrate;Sodium bitartrate;L-Tartaric acid sodium salt;SODIUM TARTRATE ACID;Sodium bitartrate monohydrate;Sodium tartrate monobasic monohydrate;Tartaric acid monosodium salt;Sodium hydrogentartrate;sodium,2,3,4-trihydroxy-4-oxobutanoate;Monosodium tartrate;SodiuM acid tartrate;SodiuM hydrogen tartrate, for analysis;Monobasic sodium tartrate;Monosodium L-(+)-tartrate;Sodium hydrogen tartrate;sodium 3-carboxy-2,3-dihydroxypropanoate;Natriumtartrat [German];Tartaric acid, monosodium salt;Natrium hydrogen-(2R,3R)-tartrat;Sodium hydrogen tartrate, 98+%, for analysis;E335;Weinstein;Butanedioic acid, 2,3-dihydroxy-, sodium salt (1:1), (2R,3R)-rel-;Butanedioic acid, 2,3-dihydroxy-, monosodium salt, (2R,3R)-rel-;Butanedioic acid, 2,3-dihydro;Sodium rel-(2R,3R)-3-carboxy-2,3-dihydroxypropanoate;SODIUM BITARTRATE [MART.];Sodium hydrogen L-tartrate, anhydrous;Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, sodium salt (1:1);DTXSID70883423;UNII-75E63I9H07;INS-335(I);Sodium (2R,3R)-3-carboxy-2,3-dihydroxypropanoate (+/-);sodium (2R,3R)-3-carboxy-2,3-dihydroxypropanoate;AS-83565;Butanedioic acid, 2,3-dihydroxy- (theta-(theta,theta))-, monosodium salt;F71307;Sodium hydrogentartrate, p.a., 98%;SCHEMBL455023;SODIUM BITARTRATE [II];NKAAEMMYHLFEFN-ZVGUSBNCSA-M;AKOS015894433;Natriumtartrat;Sodium hydrogentartrate, 98%;EINECS 208-400-9;Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, monosodium salt;(2R,3R)-2,3-Dihydroxysuccinic acid, sodium salt;60131-40-0;sodium;(2R,3R)-2,3,4-trihydroxy-4-oxobutanoate;526-94-3;MFCD00065393;E-335(I);Butanedioic acid, 2,3-dihydroxy-, (R-(R*,R*))-, monosodium salt;INS NO.335(I);SODIUM BITARTRATE [MI];Sodium hydrogentartrate, Vetec(TM) reagent grade, 98%;L(+)-Tartaric acid monosodium salt;MONOSODIUM DL-TARTRATE;Butanedioic acid, 2,3-dihydroxy-(2R,3R)-, monosodium salt;DTXSID901341208;SODIUM BITARTRATE [WHO-DD];75E63I9H07;

标识符

MDL:
MFCD00065393
InChIKey:
NKAAEMMYHLFEFN-UHFFFAOYSA-M
Inchi:
1S/C4H6O6.Na/c5-1(3(7)8)2(6)4(9)10;/h1-2,5-6H,(H,7,8)(H,9,10);/q;+1/p-1
SMILES:
[Na+].O([H])C([H])(C(=O)[O-])C([H])(C(=O)O[H])O[H]
BRN:
6099125

酒石酸氢钠(526-94-3)物化性质

实验特性

  • LogP : -3.45730
  • PSA : 117.89000
  • Merck : 14,8589
  • 水溶性 : Soluble in water.
  • 沸点 : 399.3°Cat760mmHg
  • 熔点 : 253 °C (dec.) (lit.)
  • 闪点 : 209.4°C
  • 溶解度 : H2O: 0.1 M at 20 °C, clear, colorless
  • 颜色与性状 : 无色结晶或白色结晶性粉末
  • 稳定性 : Stable. Incompatible with strong oxidizing agents.
  • 溶解性 : 溶于水,不溶于乙醇,水溶液呈碱性。
  • 敏感性 : 对湿度敏感
  • 光学活性 : [α]20/D +24°, c = 3 in H2O

计算特性

  • 精确分子量 : 171.99800
  • 氢键供体数量 : 3
  • 氢键受体数量 : 6
  • 可旋转化学键数量 : 3
  • 同位素质量 : 171.998
  • 重原子数量 : 11
  • 复杂度 : 157
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 2
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 118

酒石酸氢钠(526-94-3)安全信息

酒石酸氢钠(526-94-3)国际标准相关数据

EINECS:
208-400-9

酒石酸氢钠(526-94-3)海关数据

海关编码:
2918199090
海关数据:

中国海关编码:

2918199090

概述:

HS: 2918199090. 其他含醇基但不含其他含氧基羧酸(包括其酸酐、酰卤化物、过氧化物和过氧酸及该税号的衍生物). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2918199090 other carboxylic acids with alcohol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

酒石酸氢钠(526-94-3)生产方法和用途

用途:
用作分析试剂,也用于培养基的制备
可作生化试剂
检验钾、培养基。

酒石酸氢钠(526-94-3)参考资料

Beilstein:
6099125
PubChem CID:

酒石酸氢钠(526-94-3) MSDS

基础信息

Name:Sodium Hydrogen Tartrate Monohydrate Material Safety Data Sheet
Synonym:Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, monosodium salt, monohydrate; Sodium hydrogen tartrate monohydrate
CAS:526-94-3
Section 1 - Chemical Product ? MSDS Name:Sodium Hydrogen Tartrate Monohydrate Material Safety Data Sheet
Synonym:Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, monosodium salt, monohydrate; Sodium hydrogen tartrate monohydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
526-94-3Sodium bitartrate monohydrate100unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
May cause kidney damage.

Section 4 - FIRST AID MEASURES
? Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts may be combustible when exposed to heat, flame, or oxidizing agents.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 526-94-3: CAS# 6131-98-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Crystalline powder
Color: white
Odor: none reported
pH: acidic in solution
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not applicable.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 426 deg F
Solubility in water: Soluble.
Specific Gravity/Density: Not available.
Molecular Formula: C4H6O6.Na.H2O
Molecular Weight: 190.09

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 526-94-3: WW8225000 CAS# 6131-98-2 unlisted.
LD50/LC50:
CAS# 526-94-3: Oral, mouse: LD50 = 4360 mg/kg.
CAS# 6131-98-2.
Carcinogenicity:
Sodium hydrogen tartrate, anhydrous - Not listed by ACGIH, IARC, or NTP.
Sodium bitartrate monohydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 526-94-3: 1
CAS# 6131-98-2: No information available.
Canada
CAS# 526-94-3 is listed on Canada's DSL List.
CAS# 526-94-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 6131-98-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 526-94-3 is listed on the TSCA inventory.
CAS# 6131-98-2 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A