546-93-0 (碳酸镁,Magnesium carbonate)

结构式:
CAS号:
546-93-0
中文名称:
碳酸镁
英文名称:
Magnesium carbonate
分子式:
CMgO3
分子量:
84.3139009475708
简介:
碳酸镁(Magnesium carbonate)白色单斜结晶或无定形粉末。无毒、无味气中稳定。可用作耐火材料、锅炉和管道的保温材料,以及食品、药品、化妆品、橡胶、墨水等的添加剂。

碳酸镁(546-93-0)名称与标识符

名称

中文别名:
碳酸镁;无水碳酸镁;板蓝根颗粒;碱式碳酸镁(特级);轻质碳酸镁;碳酸镁 USP标准品;碳酸镁 医药级 USP;碳酸镁(轻质碳酸镁);碳酸镁,无水;碳酸镁医药级;医药级碳酸镁;重质碳酸镁;碳酸镁(医药级);碳酸镁(1:1);药用碳酸镁;
英文别名:
Magnesite;Carbonic acid,magnesium salt (1:1);Magnesium carbonate;MagnesiuM carbonate, for biocheMistry, specified according to the requireMents of USP;Magnesium carbonate, specified according to the requirements of USP;Magmaster;Kimboshi;Apolda;Destab;Magfy;Magnesite dust;Carbonic acid, magnesium salt;Carbonic acid, magnesium salt (1:1);Carbonate magnesium;Hydromagnesite;Magnesium carbonate (1:1);Magnesium carbonate anhydrous;Caswell No. 530;MA 70 (carbonate);GP 20 (carbonate);Gold Star (carbonate);Stan-mag magnesium carbonate;Magnesium carbonate [USAN];DCI light magnesium carbonate;Magnesium carbonate (MgCO3);Magnesium(II) carbonate (1;Australian magnesite;695808-81-2;13717-00-5;53678-75-4;E-504(i);HEAVY MAGNESIUM CARBONATE;MAGNESIUM CARBONATE, LIGHT AR;ANHYDROUS MAGNESIUM CARBONATE [MART.];0IHC698356;MAGNESIUM CARBONATE [WHO-DD];Light magnesium carbonate;DTXSID4049660;NSC 83511;Magnesium Carbonate Microparticles;CHEBI:31793;Carbonic Acid Magnesium Salt;CHEMBL1200736;E504;DB-255103;NS00074347;Magnesium (as carbonate);Magnesiumkarbonat;EC 208-915-9;Magnesium carbonate; Magnesium carbonate light; Hydrated basic magnesium carbonate;EO]-;AKOS015903527;AI3-00768;EINECS 231-817-2;magnesium;carbonate;Magnesium carbonate gold star;Humco Dewees Carminative;Giobertite;Ins-504(i);Magnesium Carbonate Light;EINECS 208-915-9;CI 77713;546-93-0;Magnesium(II) carbonate (1:1);EPA Pesticide Chemical Code 073503;HSDB 211;NSC-83511;MgCO3;Magnesite (Mg(CO3));DB09481;Q407931;Magnesium, [carbonato(2-)-;MFCD00064632;7757-69-9;C.I. 77713;CS-B1764;Carbonic acid, magnesium salt (1:?);Magnesium carbonate,light;USEPA/OPP Pesticide Code: 073503;DB-254188;Anhydrous magnesium carbonate;UNII-0IHC698356;Magnesium carbonicum 6;Ins no.504(i);Magnesio carbonato;Magnesium carbonate powder 1-5 micron;208-915-9;FM32755;Magnesium carbonate - heavy;

标识符

MDL:
MFCD00064632
InChIKey:
ZLNQQNXFFQJAID-UHFFFAOYSA-L
Inchi:
1S/CH2O3.Mg/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
SMILES:
[Mg+2].[O-]C(=O)[O-]

碳酸镁(546-93-0)物化性质

实验特性

  • LogP : 0.22240
  • PSA : 57.53000
  • 折射率 : Index of refraction: 1.536 (alpha), 1.741 (beta)
  • 沸点 : 333.6°Cat760mmHg
  • 熔点 : 990°C
  • 蒸气压 : No data available
  • 闪点 : 169.8°C
  • 溶解度 : White, friable masses or bulky, white powder; at about 700 °C is converted to MgO; sol in about 3,300 parts CO2-free water; more sol in water containing CO2; sol in dilute acids with effervescence; insol in alcohol /Magnesium carbonate hydroxide/
  • 颜色与性状 : 白色结晶固体 或结晶粉末
  • 密度 : 0.20~0.25g/ml

计算特性

  • 精确分子量 : 84.3139g/mol
  • 氢键供体数量 : 0
  • 氢键受体数量 : 3
  • 可旋转化学键数量 : 0
  • 同位素质量 : 83.969786
  • 重原子数量 : 5
  • 复杂度 : 18.8
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 氢键受体计数 : 3
  • 拓扑极表面积 : 63.2
  • 同位素原子计数 : 0
  • 拓扑分子极性表面积 : 63.2

碳酸镁(546-93-0)国际标准相关数据

EINECS:
211

碳酸镁(546-93-0)生产方法和用途

用途:

一,用于医药、橡胶工业

二,用作制造中和胃酸和治疗十二指肠溃疡的药物

三,用于制造镁盐、氧化镁、防火涂料、油墨、玻璃、牙膏、橡胶填料等,食品中用作面粉改良剂、面包膨松剂等。我国规定可作为面粉处理剂,最大使用量为5.0g/kg;在小麦粉中最大使用量1.5g/kg(面粉中)。

生产方法:

将等量的结晶硫酸镁和碳酸钠分别溶于10倍量的水中,加热至60~80℃充分混合,在产生CO2的同时生成沉淀;过滤出沉淀,用70~80℃的热水充分混合、洗涤;最后在50~60℃下干燥得产品。MgSO4+Na2CO3→Na2S04+MgCO3↓

碳酸镁(546-93-0) MSDS

基础信息

Name:Magnesium carbonate anhydrous Material Safety Data Sheet
Synonym:Carbonate magnesium; Carbonic acid magnesium salt; Magnesite
CAS:546-93-0
Section 1 - Chemical Product ? MSDS Name:Magnesium carbonate anhydrous Material Safety Data Sheet
Synonym:Carbonate magnesium; Carbonic acid magnesium salt; Magnesite

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
546-93-0Magnesium carbonate100208-915-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
Ingestion:
No hazard expected in normal industrial use. Used as antacid.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic, long-term exposure to dust may lead to "benign pneumoconiosis."

Section 4 - FIRST AID MEASURES
? Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 546-93-0: United Kingdom, WEL - TWA: 10 mg/m3 TWA (inhalable dust); 4 mg/m3 (respirable dust) United Kingdom, WEL - STEL: 30 mg/m3 STEL (inhalable dust); 12 mg STEL (respirable dust) United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Belgium - TWA: 10 mg/m3 VLE France - VME: 10 mg/m3 VME Malaysia: 10 mg/m3 TWA (particulate matter containing no asbestos <1% crystalline sili Netherlands: 10 mg/m3 MAC Russia: 10 mg/m3 TWA Spain: 10 mg/m3 VLA-ED (this value is for the particulated matter that is free from asb Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: 0 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 350 deg C (dec)
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 350 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: 3.04 g/cm3
Molecular Formula: MgCO3
Molecular Weight: 84.31

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong acids, formaldehyde.
Hazardous Decomposition Products:
Carbon dioxide, oxides of magnesium.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 546-93-0: OM2470000 LD50/LC50:
Not available.
Carcinogenicity:
Magnesium carbonate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 546-93-0: No information available.
Canada
CAS# 546-93-0 is listed on Canada's DSL List.
CAS# 546-93-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 546-93-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A