596-69-0 (18-羟孕酮,18-Hydroxyprogesterone)

结构式：

CAS号：

596-69-0

中文名称：

18-羟孕酮

英文名称：

18-Hydroxyprogesterone

分子式：

C₂₁H₃₀O₃

分子量：

330.461106777191

18-羟孕酮(596-69-0)名称与标识符

中文别名：

18-羟孕酮;

英文别名：

Pregn-4-ene-3,20-dione,18-hydroxy- (8CI,9CI);18-hydroxypregn-4-ene-3,20-dione;18-Hydroxyprogesterone;

InChIKey：

QFNCSEWPJSDMED-OFELHODLSA-N

Inchi：

1S/C21H30O3/c1-13(23)17-5-6-19-16-4-3-14-11-15(24)7-9-20(14,2)18(16)8-10-21(17,19)12-22/h11,16-19,22H,3-10,12H2,1-2H3/t16-,17-,18+,19+,20+,21+/m1/s1

SMILES：

OC[C@]12CC[C@@H]3[C@@]4(C)CCC(C=C4CC[C@H]3[C@@H]1CC[C@@H]2C(C)=O)=O

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1. Chapter 14. Biological chemistry. Part (ii) Steroids
D. N. Kirk Annu. Rep. Prog. Chem. Sect. B: Org. Chem. 1975 72 366
2. Synthesis of 11-deoxy-18-hydroxycorticosterone and 18-hydroxycorticosterone 21-acetates
Derek H. R. Barton,Michael J. Day,Robert H. Hesse,Maurice M. Pechet J. Chem. Soc. Perkin Trans. 1 1975 2252
3. Synthesis of 18-substituted steroids. Part I. 18,21-Dihydroxypregn-4-ene-3,20-dione (18-hydroxydeoxycorticosterone)
David N. Kirk,Maruthiandan S. Rajagopalan J. Chem. Soc. Perkin Trans. 1 1975 1860
4. Synthesis of 18,21-dihydroxypregn-4-ene-3,20-dione (‘18-hydroxy-deoxycorticosterone’)
David N. Kirk,Maruthiandan S. Rajagopalan J. Chem. Soc. Chem. Commun. 1974 145
5. Ready formation of enol ethers in steroidal 20β-hydroxy-18-methyl-18-ketones
George R. Lenz J. Chem. Soc. Chem. Commun. 1978 241
6. Steroids: reactions and partial syntheses
V. Cerny Nat. Prod. Rep. 1994 11 419
7. 788. Steroidal αβ-epoxy-ketones. Part I. Rearrangement of 4α,5-epoxy-5α-cholestan-3-one and its 4β,5β-isomer by means of the boron trifluoride–ether complex
D. J. Collins J. Chem. Soc. 1959 3919
8. Index of subjects
Annu. Rep. Prog. Chem. 1960 57 545
9. 18-Substituted steroids. Part 5. Further studies on the synthesis of 11β,18,21-trihydroxypregn-4-ene-3,20-dione (‘18-hydroxycorticoster-one’)
David N. Kirk,Christopher J. Slade J. Chem. Soc. Perkin Trans. 1 1980 2591