66009-10-7 (蜜二糖,一水,D-Glucose, 6-O-a-D-galactopyranosyl-, monohydrate(9CI))

CAS号:
66009-10-7
中文名称:
蜜二糖,一水
英文名称:
D-Glucose, 6-O-a-D-galactopyranosyl-, monohydrate(9CI)
分子式:
C12H24O12
分子量:
360.311765670776
相关分类:

蜜二糖,一水(66009-10-7)名称与标识符

名称

中文别名:
D(+)-蜜二糖单水合物;D-(+)-蜜二糖一水合物;4-(三氟乙酰氨基)苯酚;6-O-a-D-吡喃半乳糖基-D-葡萄糖;蜜二糖 水合物;6-O-α-D-吡喃半乳糖基-D-葡萄糖;small>-(+)-蜜二糖一水合物;α-D-蜜二糖;蜜二糖;蜜二糖,一水;6-O-α-D-吡喃半乳糖基-D-吡喃葡萄糖 一水合物;蜜二糖单水合物;
英文别名:
D-Glucose, 6-O-a-D-galactopyranosyl-, monohydrate(9CI);D-(+)-Melibiose Monohydrate;6-O-α-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE;<small>D<;D-MELIBIOSE MONOHYDRATE;MELIBIOSE MONOHYDRATE;MELIBIOSE MONOHYDRATE FOR BIOCHEMISTRY;6-O-α-D-Galactopyranosyl-D-glucopyranose Monohydrate;Melibiose, >=98% (HPLC);(2R,3S,4R,5R)-2,3,4,5-tetrahydroxy-6-{[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}hexanal hydrate;D-Melibiose hydrate;585-99-9 (anhydrous);6-alpha-D-Galactopyranosyl-D-glucopyranose;66009-10-7;6-O-A-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE;MFCD00198188;D(+)-MELIBIOSE MONOHYDRATE;D91274;CS-0199202;6-O-(a-D-Galactopyranosyl)-D-glucopyranose monohydrate;10030-63-4;D-(+)-Melibiose hydrate;(2R,3S,4R,5R)-2,3,4,5-tetrahydroxy-6-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyhexanal;hydrate;(2R,3S,4R,5R)-2,3,4,5-Tetrahydroxy-6-(((2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)hexanal hydrate;6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSEMONOHYDRATE;6-O-(a-D-Galactopyranosyl)-D-glucopyranose hydrate;?-MELIBIOSE HYDRATE;6-O-ALPHA-D-GALACTOPYRANOSYL-D-GLUCOSE MONOHYDRATE;DB-229573;CHIDEFLSUMQFBY-CQIZOMOZSA-N;

标识符

MDL:
MFCD00198188
InChIKey:
CHIDEFLSUMQFBY-CQIZOMOZSA-N
Inchi:
1S/C12H22O11.H2O/c13-1-4(15)7(17)8(18)5(16)3-22-12-11(21)10(20)9(19)6(2-14)23-12;/h1,4-12,14-21H,2-3H2;1H2/t4-,5+,6+,7+,8+,9-,10-,11+,12-;/m0./s1
SMILES:
O1[C@@H]([C@@H]([C@H]([C@H]([C@H]1CO)O)O)O)OC[C@H]([C@H]([C@@H]([C@H](C=O)O)O)O)O.O

蜜二糖,一水(66009-10-7)物化性质

实验特性

  • LogP : -5.61890
  • PSA : 206.60000
  • Merck : 5820
  • 沸点 : 730.4°C at 760 mmHg
  • 熔点 : 176-181 °C
  • 闪点 : 395.5°C
  • 溶解度 : H2O: 0.1 g/mL, clear, colorless
  • 颜色与性状 : 白色无气味的结晶粉末

计算特性

  • 精确分子量 : 360.12700
  • 氢键供体数量 : 9
  • 氢键受体数量 : 12
  • 可旋转化学键数量 : 8
  • 同位素质量 : 360.127
  • 重原子数量 : 24
  • 复杂度 : 367
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 9
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 拓扑分子极性表面积 : 198A^2

蜜二糖,一水(66009-10-7)安全信息

蜜二糖,一水(66009-10-7)海关数据

海关编码:
29389090

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蜜二糖,一水(66009-10-7)相关文献

蜜二糖,一水(66009-10-7)参考资料

Reaxys RN:
1292781
Beilstein:
31,421
PubChem CID:

蜜二糖,一水(66009-10-7) MSDS

基础信息

Name:D (+) Melibiose Monohydrate Material Safety Data Sheet
Synonym:6-D-Galactopyranosyl-D-glucopyranose monohydrat
CAS:66009-10-7
Section 1 - Chemical Product ? MSDS Name:D (+) Melibiose Monohydrate Material Safety Data Sheet
Synonym:6-D-Galactopyranosyl-D-glucopyranose monohydrat

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
66009-10-7D (+) Melibiose Monohydrate99+%unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
No information reported.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 66009-10-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble in water.
Specific Gravity/Density:
Molecular Formula: C12H22O11.H2O
Molecular Weight: 342.1474

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
No information found.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 66009-10-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
D (+) Melibiose Monohydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 66009-10-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 66009-10-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 66009-10-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A