6914-74-5 (1-羧基环戊烷甲酰胺,1-Carbamoylcyclopropane-1-carboxylic Acid)

CAS号:
6914-74-5
中文名称:
1-羧基环戊烷甲酰胺
英文名称:
1-Carbamoylcyclopropane-1-carboxylic Acid
安全信息:
分子式:
C5H7NO3
分子量:
129.113981485367

1-羧基环戊烷甲酰胺(6914-74-5)名称与标识符

名称

中文别名:
1-(氨基碳酰基)-1-环丙烷羧基酸;1-氨基甲酰-1-环丙烷羧酸;1-氨基羰基-1-环丙烷羧酸;1-氨基羰酰-1-环丙烷羧酸;1-甲酰胺基-1-环丙烷羧酸;1-羧基环丙烷羧酰胺;1-羧基环戊烷甲酰胺;
英文别名:
Cyclopropanecarboxylicacid, 1-(aminocarbonyl)-;1-aminocarbonylcyclopropanecarboxylic acid;1-carbamoylcyclopropane-1-carboxylic acid;1-CARBOXYCYCLOPROPANECARBOXAMIDE;1-(Aminocarbonyl)-1-cyclopropanecarboxylic acid;1-Carbamoyl-cyclopropancarbonsaeure;1-carbamoyl-cyclopropanecarboxylic acid;1-carboxycyclopropane-1-carboxamide;Cyclopropan-dicarbonsaeure-(1.1)-monoamid;Cyclopropane,5;1-(aminocarbonyl)-1-cyclopropane carboxylic acid;6914-74-5;1-(Aminocarbonyl)-1-cyclopropanecarboxylic acid, 97%;CS-0088462;MFCD00190650;J-503482;DTXSID20369823;1-(aminocarbonyl)-1-cyclopropane-carboxylic acid;Z951182684;GG-0709;1-carbamoylcyclopropanecarboxylicacid;1-(aminocarbonyl)-1-cyclopropan-carboxylic acid;FT-0636288;Cyclopropanecarboxylic acid, 1-(aminocarbonyl)-;SDHXFKBMHSJXHA-UHFFFAOYSA-N;E85392;EN300-69070;Cyclopropane, 5;SCHEMBL612927;BDBM82144;1-carbamoylcyclopropanecarboxylic acid;AKOS009157270;DB-019103;

标识符

MDL:
MFCD00190650
InChIKey:
SDHXFKBMHSJXHA-UHFFFAOYSA-N
Inchi:
1S/C5H7NO3/c6-3(7)5(1-2-5)4(8)9/h1-2H2,(H2,6,7)(H,8,9)
SMILES:
OC(C1(C(N)=O)CC1)=O

1-羧基环戊烷甲酰胺(6914-74-5)物化性质

实验特性

  • LogP : 0.03680
  • PSA : 80.39000
  • 折射率 : 1.4220 (estimate)
  • 沸点 : 239.15°C (rough estimate)
  • 熔点 : 185 °C (dec.) (lit.)
  • 蒸气压 : 0.0±2.2 mmHg at 25°C
  • 闪点 : 214.9±22.9 °C
  • 颜色与性状 : 不可用
  • 溶解性 : 不可用
  • 密度 : 1.3816 (rough estimate)

计算特性

  • 精确分子量 : 129.04300
  • 氢键供体数量 : 2
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 2
  • 同位素质量 : 129.043
  • 重原子数量 : 9
  • 复杂度 : 171
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : -0.8
  • 互变异构体数量 : 2
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 80.4A^2

1-羧基环戊烷甲酰胺(6914-74-5)海关数据

海关编码:
2924299090
海关数据:

中国海关编码:

2924299090

概述:

2924299090. 其他环酰胺(包括环氨基甲酸酯)(包括其衍生物以及他们的盐). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途, 包装

Summary:

2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

1-羧基环戊烷甲酰胺(6914-74-5)上下游

1-羧基环戊烷甲酰胺(6914-74-5)参考资料

Reaxys RN:
PubChem CID:

1-羧基环戊烷甲酰胺(6914-74-5) MSDS

基础信息

Name:1-(Aminocarbonyl)-1-cyclopropanecarboxylic acid, 97% Material Safety Data Sheet
Synonym:None.
CAS:6914-74-5
Section 1 - Chemical Product MSDS Name: 1-(Aminocarbonyl)-1-cyclopropanecarboxylic acid, 97% Material Safety Data Sheet
Synonym: None.
SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
6914-74-51-(Aminocarbonyl)-1-cyclopropanecarbox97unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38
SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.
SECTION 4 - FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.
SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 6914-74-5: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point: 185 deg C (dec)
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 185 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H7NO3
Molecular Weight: 129.12
SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6914-74-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-(Aminocarbonyl)-1-cyclopropanecarboxylic acid - Not listed by ACGIH, IARC, or NTP.
SECTION 12 - ECOLOGICAL INFORMATION
SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.
SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.
SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 37/39 Wear suitable gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 6914-74-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 6914-74-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6914-74-5 is not listed on the TSCA inventory. It is for research and development use only.
SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 3/08/1999 Revision #2 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A