71277-79-7 (甘草酸二钠,DISODIUM GLYCYRRHIZATE)

甘草酸二钠;甘草甜素二钠;甘草酸二钠盐;甘草酸钠;甘草甜味素;

DISODIUM GLYCYRRHIZATE;Disodium glycyrhetate;2-O-β-D-Glucopyranosyl-(20β-carboxy-11-oxo-30-norolean-12-en-3β-yl)-α-D-glucopyranosiduronic acid disodium salt;(3beta,20beta)-20-Carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-beta-D-glucopyranuronosyl-alpha-D-glucopyranosiduronic acid sodium salt;β-glycyrrhixic acid monosodium salt;Beta-glycyrrhixic acid monosodium salt;Disodium glycyrrhizinate;UNII-L8Q0US0J7V;DISODIUM GLYCYRRHIZATE [WHO-DD];disodium;(2S,3S,4S,5R,6R)-6-[(2S,3R,4S,5S,6S)-2-[[(3S,4aR,6aR,6bS,8aS,11S,12aR,14aR,14bS)-11-carboxylato-4,4,6a,6b,8a,11,14b-heptamethyl-14-oxo-2,3,4a,5,6,7,8,9,10,12,12a,14a-dodecahydro-1H-picen-3-yl]oxy]-6-carboxylato-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate;Glycyrrhizinic acid disodium salt;71277-79-7;L8Q0US0J7V;DISODIUM GLYCYRRHIZATE [INCI];Disodium glycyrrhizin;CCRIS 1966;Glycyrrhizinate, disodium;alpha-D-Glucopyranosiduronic acid, (3-beta,20-beta)-20-carboxy-11-oxo-30-norolean-12-en-3-yl-2-O-beta-D-glucopyranuronosyl-, disodium salt;Q27282842;

KPQJOKRSYYJJEL-VLQRKCJKSA-K

1S/C42H62O16.2Na/c1-37(2)21-8-11-42(7)31(20(43)16-18-19-17-39(4,36(53)54)13-12-38(19,3)14-15-41(18,42)6)40(21,5)10-9-22(37)55-35-30(26(47)25(46)29(57-35)33(51)52)58-34-27(48)23(44)24(45)28(56-34)32(49)50;;/h16,19,21-31,34-35,44-48H,8-15,17H2,1-7H3,(H,49,50)(H,51,52)(H,53,54);;/q;2*+1/p-3/t19-,21-,22-,23-,24-,25-,26-,27+,28-,29-,30+,31+,34-,35-,38+,39-,40-,41+,42+;;/m0../s1

[Na+].[Na+].O([C@@H]1[C@@H]([C@H]([C@@H]([C@@H](C(=O)[O-])O1)O)O)O[C@H]1[C@@H]([C@H]([C@@H]([C@@H](C(=O)[O-])O1)O)O)O)[C@H]1CC[C@@]2(C)[C@@H](CC[C@@]3(C)[C@]4(C)CC[C@@]5(C)CC[C@@](C(=O)[O-])(C)C[C@H]5C4=CC([C@@H]32)=O)C1(C)C

由甘草甜素与钠碱进行部分中和后精制而成。甘草粉加五倍水煮沸抽提，滤去固形物，加稀硫酸至呈弱酸性。室温下放置至析出物沉降，除去上澄清液，沉淀经水洗后用氨水中和、过滤、滤液加醋酸使甘草甜素铵析出，用70%～80%乙醇重结晶，按理论值加入碳酸钠水溶液，减压浓缩而得。