72086-72-7 (N-叔丁氧羰基-L-谷氨酸-1-甲酯,N-Boc-L-glutamic Acid a-Methyl Ester)

快速询单

结构式：

N-叔丁氧羰基-L-谷氨酸-1-甲酯MOL文件

CAS号：

72086-72-7

中文名称：

N-叔丁氧羰基-L-谷氨酸-1-甲酯

英文名称：

N-Boc-L-glutamic Acid a-Methyl Ester

分子式：

C₁₁H₁₉NO₆

分子量：

261.27166390419

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)名称与标识符

名称

中文别名：

N-叔丁氧羰基-L-谷氨酸-1-甲酯;N-叔丁氧羰基-L-谷氨酸 1-甲酯;(S)-4-((叔丁氧基羰基)氨基)-5-甲氧基-5-氧代戊酸;

英文别名：

L-Glutamic acid,N-[(1,1-dimethylethoxy)carbonyl]-, 1-methyl ester;N-Boc-L-glutamic Acid α-Methyl Ester;Boc-Glu-OMe;(S)-4-((tert-Butoxycarbonyl)amino)-5-methoxy-5-oxopentanoic acid;Boc-L-glutamic acid α-methyl ester;(L)-Boc-Glu-OCH3;A-methyl ester;Boc-L-glutamic acid;Boc-L-glutamic acid 1-methyl ester;L-BocNH-Glu-OMe;(S)-4-((tert-Butoxy(hydroxy)methylene)amino)-5-methoxy-5-oxopentanoic acid;Boc-L-glutamic acid alpha -methyl ester;(4S)-4-(tert-butoxycarbonylamino)-5-methoxy-5-oxo-pentanoic acid;DTXSID60427017;(S)-2-tert-butoxycarbonylamino-pentanedioic acid 1-methyl ester;(4S)-5-methoxy-4-[(2-methylpropan-2-yl)oxycarbonylamino]-5-oxopentanoic acid;CS-W005006;AM81698;SCHEMBL2306568;BocNH-Glu-OMe;(S)-4-((tert-Butoxycarbonyl)amino)-5-methoxy-5-oxopentanoicacid;(S)-4-(tert-butoxycarbonylamino)-5-methoxy-5-oxopentanoic acid;Boc-L-Glutamic acid methyl ester;DS-14379;A837419;MFCD00076931;ZAYAFKXUQMTLPL-ZETCQYMHSA-N;EN300-1090727;(4S)-4-{[(tert-butoxy)carbonyl]amino}-5-methoxy-5-oxopentanoic acid;Boc-L-glutamic acid a-methyl ester;N-Boc-L-glutamic Acid alpha-Methyl Ester;72086-72-7;AKOS015920012;AKOS030240852;AKOS025395629;N-Boc-L-glutamic Acid a-Methyl Ester; N-[(1,1-Dimethylethoxy)carbonyl]-L-glutamic Acid 1-Methyl Ester; N-(tert-Butoxycarbonyl)glutamic Acid a-Methyl Ester;;

标识符

MDL：

MFCD00076931

InChIKey：

ZAYAFKXUQMTLPL-ZETCQYMHSA-N

Inchi：

1S/C11H19NO6/c1-11(2,3)18-10(16)12-7(9(15)17-4)5-6-8(13)14/h7H,5-6H2,1-4H3,(H,12,16)(H,13,14)/t7-/m0/s1

SMILES：

O(C(N[C@H](C(=O)OC)CCC(=O)O)=O)C(C)(C)C

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)物化性质

实验特性

LogP : 1.30840
PSA : 101.93000
沸点 : 428.4℃ at 760 mmHg
熔点 : 119-123 ºC
闪点 : 212.9 °C

计算特性

精确分子量 : 261.12100
氢键供体数量 : 2
氢键受体数量 : 6
可旋转化学键数量 : 8
同位素质量 : 261.12123733g/mol
重原子数量 : 18
复杂度 : 320
同位素原子数量 : 0
确定原子立构中心数量 : 1
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
拓扑极表面积 : 102A^2
同位素原子计数 : 0
疏水参数计算参考值（XlogP） : 0.7
拓扑分子极性表面积 : 102Å²

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)安全信息

储存条件： 2-8°C

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)海关数据

海关数据：

中国海关编码：

2924199090

概述：

2924199090. 其他无环酰胺（包括无环氨基甲酸酯)(包括其衍生物及盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 包装

Summary：

2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)生产方法和用途

生产方法：

一，通过Boc-L-谷氨酸5苄酯Alpha甲酯合成N-叔丁氧羰基-L-谷氨酸 1-甲酯，收率约97%

二，通过N-叔丁氧羰基-L-谷氨酸5-苄酯合成N-叔丁氧羰基-L-谷氨酸 1-甲酯

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)推荐厂家更多厂家(37)

公司名称	手机号/电话	联系人	QQ	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
上海吉至生化科技有限公司	18117592386 021-57481218	吉至试剂	3007522982	询单
西安德而塔生物科技有限公司	18133906270 18133906270	张女士	2590956145	询单
西安德而塔生物科技有限公司	18133906270 18133906270	张女士	2590956145	询单
北京索莱宝科技有限公司	18101056239 010-50973130	龚思雨	3193328036	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
铼博（上海）生化科技有限公司	13311756052 021-60536361 13311756052 13311756131	张经理	2851717387	询单
上海一基实业有限公司	13311756131 021-60548336 QQ：2355265332 QQ:2851717387	胡经理	2355265332	询单
上海一基实业有限公司	13311756052 021-60526763 13311756052 13311756131	胡经理	2355265332	询单
上海绩祥生物科技有限公司	13093077543	陆经理	3985448220	询单

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)上下游

叔丁基叠氮酸盐叔丁氧羰基-L-谷氨酸5苄脂 l-谷氨酸苄酯 Boc-L-谷氨酸 N-苄氧羰基-L-谷氨酸1-甲酯 L-谷氨酸 N-叔丁氧羰基-O-苄基-L-谷氨酸甲酯 Boc-L-脯氨酸甲酯

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7)相关文献

1. Bioinspired design for the assembly of Glypromate? neuropeptide conjugates with active pharmaceutical ingredients
Sara C. Silva-Reis,A. Catarina V. D. dos Santos,Xerardo García-Mera,José E. Rodríguez-Borges,Ivo E. Sampaio-Dias New J. Chem. 2020 44 21049
2. Development of an activity-based chemiluminogenic probe for γ-glutamylcyclotransferase
Yukie Nohara,Keiko Taniguchi,Hiromi Ii,Shun Masuda,Hiroko Kawakami,Masakatsu Matsumoto,Yasunao Hattori,Susumu Kageyama,Toshiyuki Sakai,Susumu Nakata,Taku Yoshiya Org. Biomol. Chem. 2023 21 5977
3. Dipole effects on molecular and electronic structures in a novel conjugate of oligo(phenyleneethynylene) and helical peptide
Hidenori Nakayama,Tomoyuki Morita,Shunsaku Kimura Phys. Chem. Chem. Phys. 2009 11 3967
4. Towards sequence selective DNA binding: design, synthesis and DNA binding studies of novel bis-porphyrin peptidic nanostructures
Eric Biron,Normand Voyer Org. Biomol. Chem. 2008 6 2507
5. Synthesis of AHMOD-containing aminolipopeptides, unique bioactive peptaibiotics
Louise A. Stubbing,Iman Kavianinia,Margaret A. Brimble Org. Biomol. Chem. 2017 15 3542
6. Synthesis of AHMOD-containing aminolipopeptides, unique bioactive peptaibiotics
Louise A. Stubbing,Iman Kavianinia,Margaret A. Brimble Org. Biomol. Chem. 2017 15 3542

N-叔丁氧羰基-L-谷氨酸-1-甲酯(72086-72-7) MSDS

基础信息

Material Safety Data Sheet

Section 1. Identi?cation of the substance
Product Name: Boc-Glu-OMe
Synonyms:

Section 2. Hazards identi?cation
Harmful by inhalation, in contact with skin, and if swallowed.

Section 3. Composition/information on ingredients.
Ingredient name: Boc-Glu-OMe
CAS number: 72086-72-7

Section 4. First aid measures
    Skin contact:        Immediately wash skin with copious amounts of water for at least 15 minutes while removing
    contaminated clothing and shoes. If irritation persists, seek medical attention.
    Eye contact:        Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
    ?ushing of the eyes by separating the eyelids with ?ngers. If irritation persists, seek medical
    attention.
    Inhalation:        Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
    Ingestion:        Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section 5. Fire ?ghting measures
    In the event of a ?re involving this material, alone or in combination with other materials, use dry
    powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
    should be worn.

Section 6. Accidental release measures
    Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
    standards.
    Respiratory precaution:        Wear approved mask/respirator
    Hand precaution:        Wear suitable gloves/gauntlets
    Skin protection:        Wear suitable protective clothing
    Eye protection:        Wear suitable eye protection
    Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
    for disposal. See section 12.
    Environmental precautions: Do not allow material to enter drains or water courses.

Section 7. Handling and storage
    Handling:        This product should be handled only by, or under the close supervision of, those properly quali?ed
    in the handling and use of potentially hazardous chemicals, who should take into account the ?re,
    health and chemical hazard data given on this sheet.
    Store in closed vessels, refrigerated.
    Storage:

Section 8. Exposure Controls / Personal protection
    Engineering Controls: Use only in a chemical fume hood.
    Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
    General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. Physical and chemical properties
    Appearance:        Not speci?ed
    Boiling point:        No data
    No data
    Melting point:
    Flash point:        No data
    Density:        No data
    Molecular formula:        C11H19NO6
    Molecular weight:        261.3

Section 10. Stability and reactivity
    Conditions to avoid: Heat, ?ames and sparks.
    Materials to avoid: Oxidizing agents.
    Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section 11. Toxicological information
No data.

Section 12. Ecological information
No data.

Section 13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section 14. Transportation information
Non-harzardous for air and ground transportation.

Section 15. Regulatory information
    No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
    302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
    Title III, Section 313.

SECTION 16 - ADDITIONAL INFORMATION
N/A