7446-31-3 (硫酸锆四水合物,zirconium(4+) ion tetrahydrate disulfate)

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Section 1: Product Identification
   Chemical Name:       Zirconium (IV) sulfate tetrahydrate (99.99+%-Zr) PURATREM    
   CAS Registry Number:       7446-31-3    
   Formula:       Zr(SO4)2.4H2O    
   EINECS Number:       238-694-4    
   Chemical Family:       metal sulfate    
   Synonym:       Sulfuric acid, zirconium(4+) salt (2:1), Zirconium sulfate    

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Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       7446-31-3       100%       5mg/m3 (as Zr)       5mg/m3 (as Zr)    

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Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. This material partially hydrolyzes in water to form dilute sulfuric
   Emergency Overview:
   acid, a strong irritant.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Dust is a moderate to severe irritant to the eyes.    
   Skin Contact:       Causes irritation to skin. Symptoms include redness, itching, and pain.    
   Inhalation:       Inhalation of dust may irritate the respiratory tract. Symptoms may include coughing, shortness of breath.    
   Ingestion:       Ingestion may lead to nausea, vomiting and diarrhea.    
   Acute Health Affects:       Acidic behavior causes irritation of skin, eyes and respiratory and gastrointestinal tracts.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

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SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic fumes of sulfur oxides.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.    

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SECTION 7: Handling and Storage
   Handling and Storage:       Store material in a tightly sealed bottle away from moisture.    

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SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
   Respirator:
   Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

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SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       283.33 (355.39)    
   Melting Point:       100°C (-3H2O)    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

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SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       Strong bases    
   Decomposition Products:       In water, dilute sulfuric acid    

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SECTION 11: Toxicological Information
   Oral (rat); LD50: 3500 mg/kg. Intraperitoneal (rat); LD50: 175 mg/kg. Subcutaneous (rat); LDLo: 500 mg/kg.
   RTECS Data:
   Intratesticular (rat); TDLo: 22667 ug/kg. Mouse Lymphocyte; Unscheduled DNA synthesis: 20 umol/L.
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

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SECTION 12: Ecological Information
   Ecological Information:       No information available    

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SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

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SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

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SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    

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SECTION 16 - ADDITIONAL INFORMATION
N/A