7790-29-6 (碘化铷,rubidium iodide)

结构式:
CAS号:
7790-29-6
中文名称:
碘化铷
英文名称:
rubidium iodide
分子式:
IRb
分子量:
212.372268676758
简介:
碘化铷是一种无机化合物,化学式为RbI,常温常压下为固体。有毒,易溶于水。

碘化铷(7790-29-6)名称与标识符

名称

中文别名:
碘化铷;碘酸铷;氧化钌(IV) 水合物;
英文别名:
rubidium iodide;rubidium(1+),iodide;RutheniuM oxide hydrate;Rubidium monoiodide;Rubidiumiodide;Rubidium jodatum;SY061077;18CYW0VL2X;Rubidium iodide (99.8%-Rb);Q426446;RUBIDIUM IODIDE [MI];MFCD00011192;RUBIDIUM IODIDE [MART.];RUBIDIUM IODIDE [WHO-DD];rubidium(1+);iodide;EINECS 232-198-1;DTXSID00880081;Rubidium Iodide, anhydrous;RUBIDIUM IODIDE (MART.);NS00082270;AKOS015833260;Rubidium-iodid;D95966;A865124;DTXCID801021675;UNII-18CYW0VL2X;Rubidium iodide (RbI);Rubidium Iodatum;7790-29-6;WFUBYPSJBBQSOU-UHFFFAOYSA-M;

标识符

MDL:
MFCD00011192
InChIKey:
WFUBYPSJBBQSOU-UHFFFAOYSA-M
Inchi:
1S/HI.Rb/h1H;/q;+1/p-1
SMILES:
[I-].[Rb+]

碘化铷(7790-29-6)物化性质

实验特性

  • LogP : -2.99600
  • PSA : 0.00000
  • Merck : 14,8286
  • 折射率 : 1.6474
  • 水溶性 : 152 g/100 mL (17 ºC)
  • 沸点 : 1300 °C/1 atm(lit.)
  • 熔点 : 656 °C (lit.)
  • 闪点 : 1300°C
  • 溶解度 : ethanol: soluble(lit.)
  • 颜色与性状 : 白色结晶或结晶性粉末。
  • 稳定性 : Stable, but may be sensitive to light and air.
  • 敏感性 : Hygroscopic
  • 密度 : 3.55 g/mL at 25 °C(lit.)

计算特性

  • 精确分子量 : 211.81600
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 211.816
  • 重原子数量 : 2
  • 复杂度 : 2
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0A^2

碘化铷(7790-29-6)安全信息

碘化铷(7790-29-6)国际标准相关数据

EINECS:
232-198-1

碘化铷(7790-29-6)生产方法和用途

用途:
制药。
生产方法:
主要通过碳酸铷与纯氢碘酸反应或Rb2SO4和相当量Ba(OH)2作用,再用HI中和生成的RbOH,至无碱性反应。为了得到碳酸铷纯品,将纯RbCl加过量草酸,在铂皿中强热,转变成碳酸盐。将此残渣溶于HI中,蒸发溶液至干,熔体应不显碱性。

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碘化铷(7790-29-6)相关文献

碘化铷(7790-29-6) MSDS

基础信息

Name:Rubidium Iodide 99.9% Material Safety Data Sheet
Synonym:None known
CAS:7790-29-6
Section 1 - Chemical Product ? MSDS Name:Rubidium Iodide 99.9% Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
7790-29-6Rubidium iodide99.9232-198-1
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract. May cause kidney damage. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn..
Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms could include skin rash, running nose and headache. May cause kidney damage.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Store protected from light.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7790-29-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Crystals
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 1 mm Hg @748C
Viscosity: Not available.
Boiling Point: 1300 deg C
Freezing/Melting Point: 642 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 3.55
Molecular Formula: IRb
Molecular Weight: 212.37

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, ammonia and/or derivatives, iodine, rubidium oxides.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 7790-29-6: VL8925000 LD50/LC50:
CAS# 7790-29-6: Oral, rat: LD50 = 4708 mg/kg; Oral, rat: LD50 = 4708 mg/kg.
Carcinogenicity:
Rubidium iodide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7790-29-6: 1
Canada
CAS# 7790-29-6 is listed on Canada's NDSL List.
CAS# 7790-29-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7790-29-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A