80-26-2 (乙酸松油酯,alpha-Terpinyl acetate)

_99%

反应条件：

1.1 Catalysts: Ceric sulfate ; 3 h, 25 °C; cooled
1.2 Reagents: Sodium carbonate Solvents: Water ; basified

参考文献：

Study on the synthesis of terpinyl acetate catalyzed by cerium sulfate

Zhao, Qian-rong; et al, Yingyong Huagong, 2005, 34(12), 731-733

合成路线：1 步

_97%

反应条件：

1.1 9.9 s, 5 MPa, 200 °C

参考文献：

Environmental benign application to organic syntheses using high-pressure, high-temperature water microfluidic system

Matsushima, Keiichiro; et al, Hokkaidoritsu Kogyo Shikenjo Hokoku, 2009, 308, 23-31

合成路线：1 步

_97%

反应条件：

1.1 Solvents: Water ; 9.9 s, 5 MPa, 200 °C

参考文献：

A highly selective, high-speed, and hydrolysis-free O-acylation in subcritical water in the absence of a catalyst

Sato, Masahiro; et al, Angewandte Chemie, 2007, 46(33), 6284-6288

合成路线：1 步

18172-67-3

_98%

反应条件：

1.1 Reagents: Silica , Ceric ammonium nitrate (silica gel adsorbed) Solvents: Hexane

参考文献：

Reaction of 2(10)-pinene with CAN(MeOH)/SiO2 [cerium(IV) ammonium nitrate and methanol adsorbed on silica gel] reagent

Kurata, Takeo; et al, Yukagaku, 1989, 38(7), 553-7

合成路线：1 步

108-22-5

_93%

反应条件：

1.1 Reagents: Cyclohexanone, O-acetyloxime Catalysts: Bis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]bis(tetrahydrofu…

参考文献：

New acylation method using oxime esters in the presence of lanthanide complexes

Tashiro, D.; et al, Kidorui, 1997, 30, 296-297

合成路线：1 步

108-22-5

_91%

反应条件：

1.1 Catalysts: p-Toluenesulfonic acid ; 0 °C

参考文献：

Reaction of levoglucosenone with (±)-α-terpineol and its acetate

Galimova, Yu. S.; et al, Russian Journal of Organic Chemistry, 2014, 50(12), 1848-1850

合成路线：1 步

108-22-5

_90%

反应条件：

1.1 Reagents: Cyclohexanone, O-acetyloxime Catalysts: Bis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]bis(tetrahydrofu… Solvents: Toluene
1.2 Reagents: Water Solvents: Diisopropyl ether

参考文献：

An Efficient Acylation of Tertiary Alcohols with Isopropenyl Acetate Mediated by an Oxime Ester and Cp*2Sm(thf)2

Tashiro, Daisuke; et al, Journal of Organic Chemistry, 1997, 62(23), 8141-8144

合成路线：1 步

39864-10-3

_90%

参考文献：

Solvolytic displacement of alkyl halides by metal salts. Preparative procedures for allyl-, benzyl-, and tertiary alkyloxy derivatives using the zinc salts

Gurudutt, K. N.; et al, Tetrahedron, 1982, 38(12), 1843-6

合成路线：1 步

_88%

反应条件：

1.1 Solvents: Acetonitrile ; 8 h, reflux

参考文献：

Efficient chemoselective liquid phase acylation of amines, alcohols and bifunctional compounds over ZSM-35

Srivastava, R.; et al, Indian Journal of Chemistry, 2004, (4), 888-891

合成路线：1 步

反应条件：

1.1 Catalysts: Ferric sulfate Solvents: Acetic acid ; 3 h, 338 K

参考文献：

Fe(SO4)3-Catalyzed Synthesis of Terpenic Alcohols Esters: A Simple and Bifunctional Reusable Solid Catalyst

da Silva, Marcio J.; et al, ChemistrySelect, 2018, 3(21), 5742-5748

合成路线：1 步

反应条件：

1.1 Catalysts: Triacylglycerol lipase Solvents: Carbon dioxide , Heptane ; 1.5 h, 10 MPa, 50 °C

参考文献：

Lipase-catalyzed production of a bioactive terpene ester in supercritical carbon dioxide

Liu, Kuan-Ju; et al, Journal of Biotechnology, 2010, 146(4), 215-220

合成路线：1 步

_87%

反应条件：

1.1 Catalysts: Nitric acid , Polyaniline ; rt → 60 °C; 8 h, 60 °C

参考文献：

Preparation and esterification properties of polyaniline nanofibers

Zheng, Xiao-ying; et al, Kunming Yejin Gaodeng Zhuanke Xuexiao Xuebao, 2011, 27(1), 27-30

合成路线：1 步

_83%

反应条件：

1.1 Catalysts: Tin tetrachloride ; 5 h, 25 - 30 °C
1.2 Reagents: Sodium carbonate Solvents: Water ; basified

参考文献：

Synthesis of terpinyl acetate catalyzed by SnCl4·5H2O

Zhao, Qian-rong; et al, Hecheng Huaxue, 2006, 14(3), 290-292

合成路线：1 步

_81%

反应条件：

1.1 Catalysts: Niobium pentoxide , Sulfate , Tin oxide (SnO2) ; 3 h, 50 °C

参考文献：

Preparation of solid superacid SO42-/SnO2-Nb2O5 by a new technology and its application to catalyze the esterification of terpineol

Huang, Jian-tuan; et al, Huaxue Yanjiu Yu Yingyong, 2012, 24(6), 940-947

合成路线：1 步

2131736-77-9

_87%

反应条件：

1.1 Reagents: Hydrochloric acid Solvents: Ethyl acetate ; 48 h, rt
1.2 Reagents: Sodium bicarbonate Solvents: Water ; rt
1.3 Reagents: Silica Solvents: Ethyl acetate ; 12 h, rt

参考文献：

m-C2B10H11HgCl/AgOTf-Catalyzed Reaction for Reductive Deoxygenation

Yamasaki, Naoto; et al, Synlett, 2018, 29(2), 169-175

合成路线：1 步

1126-35-8

_85%

参考文献：

Solvolytic displacement of alkyl halides by metal salts. Preparative procedures for allyl-, benzyl-, and tertiary alkyloxy derivatives using the zinc salts

Gurudutt, K. N.; et al, Tetrahedron, 1982, 38(12), 1843-6

合成路线：1 步

_83%

反应条件：

1.1 Reagents: Perchloric acid , Silica ; 5 min, rt

参考文献：

Structure-activity relationships of monoterpenes and acetyl derivatives against Aedes aegypti (Diptera: Culicidae) larvae

Pandey, Satish K.; et al, Pest Management Science, 2013, 69(11), 1235-1238

合成路线：1 步

39864-10-3

557-34-6

_70%

反应条件：

1.1 Reagents: Potassium carbonate Solvents: Chloroform

参考文献：

Sonochemical acetylation reactions of tertiary alkyl halides

Jayasree, J.; et al, Synthetic Communications, 1996, 26(6), 1103-7

合成路线：1 步

80-56-8

_53%

反应条件：

1.1 Solvents: Dichloromethane , Water ; 4 h, 40 °C

参考文献：

Heterogeneous zeolite-based catalyst for esterification of α-pinene to α-terpinyl acetate

Wijayati, Nanik; et al, Oriental Journal of Chemistry, 2019, 35(1), 399-403

合成路线：1 步

80-56-8

_23%

反应条件：

1.1 Catalysts: Alumina , Silica ; 4 h, 20 °C
1.2 24 h, 20 °C
1.3 Reagents: Sodium hydroxide Solvents: Water ; neutralized

参考文献：

Study of one-step synthesis of terpinyl acetate with Hβ zeolite

Fan, Guang; et al, Fuzhou Daxue Xuebao, 2005, 33(5), 679-684

合成路线：1 步

80-56-8

反应条件：

1.1 Reagents: Chloroacetic acid Catalysts: 1-Methyl-3-(3-sulfopropyl)imidazolium dihydrogen phosphate ; rt; 10 h, 40 °C

参考文献：

Synthesis of terpinyl acetate from α-pinene catalyzed by acidic ionic liquid

Ji, Kaihui; et al, Qingdao Keji Daxue Xuebao, 2008, 29(6), 480-484

合成路线：1 步

108-05-4

反应条件：

1.1 Catalysts: Carboxyl esterase Solvents: 2,2,4-Trimethylpentane ; 40 °C

参考文献：

Whole-Cell Biocatalytic Synthesis of Cinnamyl Acetate with a Novel Esterase from the DNA Library of Acinetobacter hemolyticus

Dong, Hao; et al, Journal of Agricultural and Food Chemistry, 2017, 65(10), 2120-2128

合成路线：1 步

138-86-3

反应条件：

1.1 Catalysts: p-Toluenesulfonic acid

参考文献：

Applications of lemon oil. 2. Chromatographic study of the reaction of limonene with acetic acid catalyzed by p-toluenesulfonic acid

Ubillus, Fabiola; et al, Boletin de la Sociedad Quimica del Peru, 1990, 56(2), 71-7

合成路线：1 步

2131736-88-2

反应条件：

1.1 Reagents: Silica Solvents: Ethyl acetate ; 24 h, rt

参考文献：

m-C2B10H11HgCl/AgOTf-Catalyzed Reaction for Reductive Deoxygenation

Yamasaki, Naoto; et al, Synlett, 2018, 29(2), 169-175

合成路线：1 步

470-82-6

反应条件：

1.1 Catalysts: Palladium ; 2 h, rt

参考文献：

Valorization of Monoterpene Hydrocarbon Fraction of Essential Oil to High-Value Oxygenated Monoterpenoids by Solvent-Free Catalytic Modification Using 1%Pd-β-Zeolite

Gupta, Madhuri; et al, Waste and Biomass Valorization, 2023, 14(2), 619-630

合成路线：1 步

628-63-7