814-95-9 (草酸锶,Strontium oxalate)

结构式:
CAS号:
814-95-9
中文名称:
草酸锶
英文名称:
Strontium oxalate
安全信息:
分子式:
C2H2O4Sr
分子量:
177.654883861542
简介:
草酸锶,白色结晶粉末。相对密度2.08。150℃失去结晶水。
相关分类:

草酸锶(814-95-9)名称与标识符

名称

中文别名:
草酸锶;乙二酸锶;乙二酸锶盐(1:1);
英文别名:
Strontium oxalate;Strontiumoxalateminwhitepowder;Oxalicacid, strontium salt (1:1) (8CI);Strontium oxalate (6CI,7CI);Strontiumoxalate (SrC2O4);SCHEMBL48259;Strontium oxalate, SrC2O4;Ethanedioic acid, strontium salt (1:1);strontium;oxalate;strontium(2+) oxalate;STRONTIUM OXALATE [MI];Strontiumoxalate;NSC-83515;FT-0632972;814-95-9;C2O4Sr;CX-0073;EINECS 212-415-6;Oxalic acid, monostrontium salt;UNII-7IAW7E69NI;NS00079738;ethanedioic acid strontium salt;NSC 83515;AKOS015837669;DTXSID80883590;7IAW7E69NI;STRONTIUM OXALATE (SRC2O4);Oxalic acid, strontium salt (1:1);Q7624776;Oxalic acid, strontium salt (1:1) (8CI);Strontium oxalate (6CI, 7CI);DTXCID201023104;KQAGKTURZUKUCH-UHFFFAOYSA-L;DB-056534;strontium(2+) oxalate ion;

标识符

MDL:
MFCD00050803
InChIKey:
ANBJNNOVODZPET-UHFFFAOYSA-N
Inchi:
1S/C2H2O4.Sr/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);
SMILES:
[Sr].O=C(C(O)=O)O

草酸锶(814-95-9)物化性质

实验特性

  • LogP : -0.84440
  • PSA : 74.60000
  • Merck : 13,8927
  • 沸点 : 365.1 ºC at 760 mmHg
  • 闪点 : 188.8 ºC
  • 溶解度 : Soluble in hydrochloric acid and nitric acid
  • 颜色与性状 : 白色结晶性粉末。无气味。
  • 稳定性 : Stable. Incompatible with strong acids, strong oxidizing agents.
  • 溶解性 : 易溶于稀盐酸或硝酸,溶于20000份水、1900份3.5%的乙酸。

计算特性

  • 精确分子量 : 177.90100
  • 氢键供体数量 : 0
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 0
  • 同位素质量 : 175.885
  • 重原子数量 : 7
  • 复杂度 : 60.5
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 80.3

草酸锶(814-95-9)安全信息

草酸锶(814-95-9)国际标准相关数据

EINECS:
MFCD00050803

草酸锶(814-95-9)海关数据

海关编码:
2917119000
海关数据:

中国海关编码:

2917119000

概述:

2917119000 其他草酸盐和酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

申报要素:

品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分

Summary:

2917119000 oxalic acid salts and esters VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

草酸锶(814-95-9)推荐厂家 更多厂家(59)

公司名称 手机号/电话 联系人 QQ 微信 询单
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上海源叶生物科技有限公司 15026964105
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陈盼 1400838822
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草酸锶(814-95-9)合成路线

合成路线:1 步
反应条件:
参考文献:
Thermal decomposition of strontium oxalate synthesized from mixed water-dioxane solution of different compositions
Nogtev, G. A.; et al, Izvestiya Vysshikh Uchebnykh Zavedenii, 2001, 44(3), 94-97
合成路线:1 步
反应条件:
参考文献:
Biomimetic growth of strontium oxalate aggregates with unusual morphologies in the presence of poly(methacrylic acid)
Zhang, Dongbai; et al, CrystEngComm, 2002, 4, 536-538

草酸锶(814-95-9)相关文献

草酸锶(814-95-9)参考资料

Beilstein:
212-415-6
PubChem CID:

草酸锶(814-95-9) MSDS

基础信息


Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
  Product identifiers
    Product name        : Strontium oxalate    
    CAS-No.        : 814-95-9    
  Relevant identified uses of the substance or mixture and uses advised against
    Identified uses        : Laboratory chemicals, Manufacture of substances    
  
  

Section 2. HAZARDS IDENTIFICATION
  Classification of the substance or mixture
  Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
    Acute toxicity, Dermal (Category 4)
    Acute toxicity, Oral (Category 4)
  Classification according to EU Directives 67/548/EEC or 1999/45/EC
    Harmful in contact with skin and if swallowed.
  Label elements
  Labelling according Regulation (EC) No 1272/2008 [CLP]
    Pictogram
    Signal word        Warning    
    Hazard statement(s)
    H302        Harmful if swallowed.    
    H312        Harmful in contact with skin.    
    Precautionary statement(s)
    P280        Wear protective gloves/ protective clothing.    
    Supplemental Hazard        none    
    Statements
  According to European Directive 67/548/EEC as amended.
    Hazard symbol(s)
    R-phrase(s)
    R21/22        Harmful in contact with skin and if swallowed.    
    S-phrase(s)
    S24/25        Avoid contact with skin and eyes.    
  Other hazards - none

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substances
    Formula        : C2O4Sr    
    Molecular Weight        : 175,64 g/mol    
    Component        Concentration    
  Strontium oxalate
    CAS-No.        814-95-9        -    
    EC-No.        212-415-6    
    Index-No.        607-007-00-3    

Section 4. FIRST AID MEASURES
  Description of first aid measures
  General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
  If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
  In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
  In case of eye contact
    Flush eyes with water as a precaution.
  If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
  Most important symptoms and effects, both acute and delayed
    Effects due to ingestion may include:, Vomiting, Diarrhoea, To the best of our knowledge, the chemical,
    physical, and toxicological properties have not been thoroughly investigated.
  Indication of any immediate medical attention and special treatment needed
    no data available

Section 5. FIREFIGHTING MEASURES
  Extinguishing media
  Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
  Special hazards arising from the substance or mixture
    Carbon oxides, Strontium oxides
  Advice for firefighters
    Wear self contained breathing apparatus for fire fighting if necessary.
  Further information
    no data available

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
    adequate ventilation. Avoid breathing dust.
  Environmental precautions
    Do not let product enter drains.
  Methods and materials for containment and cleaning up
    Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
    containers for disposal.
  Reference to other sections
    For disposal see section 13.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
    Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
    Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire
    protection.
  Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
  Specific end uses
    no data available

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
  Control parameters
  Components with workplace control parameters
  Exposure controls
  Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
    at the end of workday.
  Personal protective equipment
  Eye/face protection
    Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
    and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
  Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
    (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
    contaminated gloves after use in accordance with applicable laws and good laboratory practices.
    Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
    the standard EN 374 derived from it.
  Body Protection
    Complete suit protecting against chemicals, The type of protective equipment must be selected
    according to the concentration and amount of the dangerous substance at the specific workplace.
  Respiratory protection
    For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher
    level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges.
    Use respirators and components tested and approved under appropriate government standards
    such as NIOSH (US) or CEN (EU).

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Information on basic physical and chemical properties
    a) Appearance        Form: powder    
    Colour: white
    b) Odour        no data available    
    c) Odour Threshold        no data available    
    d) pH        no data available    
    e) Melting point/freezing        no data available    
    point
    f) Initial boiling point and no data available
    boiling range
    g) Flash point        no data available    
    h) Evaporation rate        no data available    
    i) Flammability (solid, gas) no data available
    j) Upper/lower        no data available    
    flammability or
    explosive limits
    k) Vapour pressure        no data available    
    l) Vapour density        no data available    
    m) Relative density        no data available    
    n) Water solubility        no data available    
    o) Partition coefficient: n- no data available
    octanol/water
    p) Autoignition        no data available    
    temperature
    q) Decomposition        no data available    
    temperature
    r) Viscosity        no data available    
    s) Explosive properties        no data available    
    t) Oxidizing properties        no data available    
  Other safety information
    no data available

Section 10. STABILITY AND REACTIVITY
  Reactivity
    no data available
  Chemical stability
    no data available
  Possibility of hazardous reactions
    no data available
  Conditions to avoid
    no data available
  Incompatible materials
    Strong oxidizing agents, Strong acids
  Hazardous decomposition products
    Other decomposition products - no data available

Section 11. TOXICOLOGICAL INFORMATION
  Information on toxicological effects
  Acute toxicity
    no data available
  Skin corrosion/irritation
    no data available
  Serious eye damage/eye irritation
    no data available
  Respiratory or skin sensitization
    no data available
  Germ cell mutagenicity
    no data available
  Carcinogenicity
    IARC:        No component of this product present at levels greater than or equal to 0.1% is identified as    
    probable, possible or confirmed human carcinogen by IARC.
  Reproductive toxicity
    no data available
  Specific target organ toxicity - single exposure
    no data available
  Specific target organ toxicity - repeated exposure
    no data available
  Aspiration hazard
    no data available
  Potential health effects
  Inhalation        May be harmful if inhaled. May cause respiratory tract irritation.    
  Ingestion        Harmful if swallowed.    
  Skin        Harmful if absorbed through skin. May cause skin irritation.    
  Eyes        May cause eye irritation.    
  Signs and Symptoms of Exposure
    Effects due to ingestion may include:, Vomiting, Diarrhoea, To the best of our knowledge, the chemical,
    physical, and toxicological properties have not been thoroughly investigated.
  Additional Information
    RTECS: Not available

Section 12. ECOLOGICAL INFORMATION
  Toxicity
    no data available
  Persistence and degradability
    no data available
  Bioaccumulative potential
    no data available
  Mobility in soil
    no data available
  Results of PBT and vPvB assessment
    no data available
  Other adverse effects
    no data available

Section 13. DISPOSAL CONSIDERATIONS
  Waste treatment methods
  Product
    Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed
    professional waste disposal service to dispose of this material. Dissolve or mix the material with a
    combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
  Contaminated packaging
    Dispose of as unused product.

Section 14. TRANSPORT INFORMATION
  UN number
    ADR/RID: -        IMDG: -        IATA: -    
  UN proper shipping name
    ADR/RID: Not dangerous goods
    IMDG: Not dangerous goods
    IATA:        Not dangerous goods    
  Transport hazard class(es)
    ADR/RID: -        IMDG: -        IATA: -    
  Packaging group
    ADR/RID: -        IMDG: -        IATA: -    
  Environmental hazards
    ADR/RID: no        IMDG Marine pollutant: no        IATA: no    
  Special precautions for user
    no data available



SECTION 15 - REGULATORY INFORMATION
N/A


SECTION 16 - ADDITIONAL INFORMATION
N/A