822-38-8 (1,3-二噻戊环-2-二酮,1,3-Dithiolane-2-thione)

反应条件：

1.1 Reagents: Triethylsilane Solvents: Acetonitrile

参考文献：

Ionic and organometallic-catalyzed organosilane reductions

Larson, Gerald L.; et al, Organic Reactions (Hoboken, 2008, 71, 1-737

合成路线：1 步

_97%

反应条件：

1.1 Solvents: Benzene ; 8 h, 60 °C

参考文献：

Sodium trithiocarbonate

Young, Jonathan R., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001, 1, 1-2

合成路线：1 步

_97%

反应条件：

1.1 Catalysts: Trioctylammonium chloride Solvents: Benzene

参考文献：

Convenient synthesis of cyclic trithiocarbonates from 1,2- or 1,3-dihaloalkanes and sodium trithiocarbonate in the presence of phase-transfer catalyst

Sugawara, Akira; et al, Bulletin of the Chemical Society of Japan, 1989, 62(1), 339-41

合成路线：1 步

_94%

反应条件：

1.1 Reagents: Cesium carbonate Solvents: Dimethyl sulfoxide ; 20 min, rt
1.2 3.5 h, rt

参考文献：

Novel and efficient method for the synthesis of cyclic trithiocarbonates employing Cs2Co3/CS2 system

Nitin, Srivastava; et al, Research Journal of Chemistry and Environment, 2021, 25(12), 142-148

合成路线：1 步

_91%

参考文献：

Synthesis of Symmetrical Dialkyl Trithiocarbonates Using a Polymer Supported System

Tamami, Bahman; et al, Journal of Chemical Research, 1998, (8), 454-455

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Cesium hydroxide Solvents: Dimethyl sulfoxide ; 60 min, 50 °C

参考文献：

Superbasic system CsOH/DMSO as a reagent for a fast one-step synthesis of symmetrical dialkyl trithiocarbonates

Yousefi, Ali, Journal of Sulfur Chemistry, 2015, 36(6), 672-677

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Disodium sulfide Solvents: Water

参考文献：

Phase-transfer synthesis of symmetrical and unsymmetrical dialkyl trithiocarbonates

Degani, Iacopo; et al, Synthesis, 1986, (11), 894-9

合成路线：1 步

_74%

反应条件：

1.1 Reagents: Potassium hydroxide Catalysts: Tetrabutylammonium bromide Solvents: Carbon disulfide ; 60 min, reflux

参考文献：

A novel one-step synthesis of symmetrical dialkyl trithiocarbonates in the presence of phase-transfer catalysis

Kiasat, Ali Reza; et al, Journal of the Chinese Chemical Society (Taipei, 2008, 55(3), 639-642

合成路线：1 步

_60%

反应条件：

1.1 Catalysts: 1635417-42-3 Solvents: Carbon disulfide ; 15 min, 25 °C
1.2 Solvents: Water ; 60 min, 50 °C

参考文献：

An Efficient and Straightforward Access to Symmetrical Dialkyl Trithiocarbonates Using a Basic Task-Specific Ionic Liquid and Carbon Disulfide

Sayyahi, Soheil; et al, Phosphorus, 2014, 189(11), 1718-1722

合成路线：1 步

624-73-7

_91%

反应条件：

1.1 Reagents: Oxygen Catalysts: Imidazole Solvents: Dimethyl sulfoxide , Water ; 8 h, 45 °C

参考文献：

An efficient one-pot approach to the synthesis of symmetric trithiocarbonates from carbon disulfide and alkyl halides using imidazole

Soleiman-Beigi, Mohammad; et al, Journal of Sulfur Chemistry, 2014, 35(5), 470-476

合成路线：1 步

_90%

反应条件：

1.1 Solvents: Benzene ; 2 h, 80 °C

参考文献：

Sodium trithiocarbonate

Young, Jonathan R., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001, 1, 1-2

合成路线：1 步

_90%

反应条件：

1.1 Solvents: Benzene

参考文献：

Convenient synthesis of cyclic trithiocarbonates from 1,2- or 1,3-dihaloalkanes and sodium trithiocarbonate in the presence of phase-transfer catalyst

Sugawara, Akira; et al, Bulletin of the Chemical Society of Japan, 1989, 62(1), 339-41

合成路线：1 步

_62%

反应条件：

1.1 Solvents: Ethanol

参考文献：

Preparation and properties of certain polymeric and cyclic trithiocarboxylates

Braun, D.; et al, Monatshefte fuer Chemie, 1965, 96(2), 631-41

合成路线：1 步

_20%

反应条件：

1.1 Reagents: Sodium hydroxide , Trioctylmethylammonium chloride Solvents: Water
1.2 Reagents: 1-Chloropropane Solvents: Benzene

参考文献：

Convenient synthesis of alkanediyl bis(alkyl trithiocarbonate)s from alkenedithiols with alkyl halides and carbon disulfide in the presence of phase-transfer catalyst

Sugawara, Akira; et al, Bulletin of the Chemical Society of Japan, 1987, 60(1), 435-7

合成路线：1 步

_58%

反应条件：

1.1 Catalysts: Trioctylammonium chloride Solvents: Benzene

参考文献：

Convenient synthesis of cyclic trithiocarbonates from 1,2- or 1,3-dihaloalkanes and sodium trithiocarbonate in the presence of phase-transfer catalyst

Sugawara, Akira; et al, Bulletin of the Chemical Society of Japan, 1989, 62(1), 339-41

合成路线：1 步

420-12-2

_53%

反应条件：

1.1 Catalysts: Triethylamine

参考文献：

The synthesis of 1,3-dithiolane-2-thione derivatives

Taguchi, Yoichi; et al, Bulletin of the Chemical Society of Japan, 1987, 60(2), 727-30

合成路线：1 步

420-12-2

_47%

反应条件：

1.1 Catalysts: Lithium tert-butoxide ; 25 °C; 24 h, 25 °C

参考文献：

Atom economical synthesis of di- and trithiocarbonates by the lithium tert-butoxide catalyzed addition of carbon disulfide to epoxides and thiiranes

Diebler, J.; et al, Organic & Biomolecular Chemistry, 2016, 14(31), 7480-7489

合成路线：1 步

420-12-2

反应条件：

1.1 Catalysts: Tetrabutylammonium fluoride ; 12 h, 80 °C

参考文献：

Organocatalytic selective coupling of episulfides with carbon disulfide for the synthesis of poly(trithiocarbonate)s and cyclic trithiocarbonates

Chen, Chao; et al, Polymer Chemistry, 2022, 13(23), 3471-3478

合成路线：1 步

109-64-8

_50%

参考文献：

Thiono and dithio esters. XXIV. Synthesis of tetrathiooxalate

Hartke, Klaus; et al, Chemische Berichte, 1980, 113(5), 1898-906

合成路线：1 步

4829-04-3

_10%

反应条件：

1.1 Reagents: S8

参考文献：

C-H activation with elemental sulfur: synthesis of cyclic thioureas from formaldehyde aminals and S8

Denk, Michael K.; et al, Chemistry - A European Journal, 2001, 7(20), 4477-4486

合成路线：1 步

140-90-9

反应条件：

1.1 Solvents: Methanol

参考文献：

New convenient method for synthesis of 1,3-dithiolane-2-thiones and their use for synthesis of 4,5-bis(methoxycarbonyl)-1,3-dithiole-2-thione

Khodorkovskii, V. Yu.; et al, Zhurnal Organicheskoi Khimii, 1985, 21(6), 1345-8

合成路线：1 步

反应条件：

1.1 Catalysts: Butyllithium

参考文献：

Generation of 1,2-ethanebis(trithiocarbonic acid) dianion from 2,2'-[1,2-ethanediylbis(thio)]-bis-1,3-dithiolane and its reaction with alkyl halides

Tanimoto, Shigeo; et al, Tetrahedron Letters, 1981, 22(7), 655-8

合成路线：1 步

反应条件：

1.1 Reagents: Disodium sulfide

参考文献：

Process for the preparation of vicinal alkanedithiols

, European Patent Organization, , ,

合成路线：1 步

33145-02-7

反应条件：

1.1 Catalysts: 1-(Chloromethoxy)butane

参考文献：

The reactions of the 1,2-ethanediylbis(trithiocarbonic acid) dianion with several electrophilic reagents

Tanimoto, Shigeo; et al, Bulletin of the Chemical Society of Japan, 1982, 55(1), 339-40

合成路线：1 步

7191-30-2

反应条件：

1.1 Solvents: Carbon disulfide

参考文献：

A new type of iminocarbonylaton of diols, mercaptoalkanol, and dithiol via their dibutylstannyl derivatives

Sakai, Shizuyoshi; et al, Bulletin of the Chemical Society of Japan, 1977, 50(12), 3271-5

合成路线：1 步

75-21-8

反应条件：

1.1 Catalysts: Lithium chloride Solvents: Dimethylformamide ; 2 h, 150 °C

参考文献：

One-pot synthesis of ethylene trithiocarbonate from ethylene carbonate

Kim, Hoon Sik; et al, Applied Catalysis, 2008, 337(2), 168-172

合成路线：2 步