87188-51-0 (叔丁基4-乙烯基苯基碳酸酯,Carbonic acid,1,1-dimethylethyl 4-ethenylphenyl ester)

_99%

反应条件：

1.1 Reagents: Tetramethylammonium hydroxide Solvents: Water ; 10 min, 0 °C; 1 h, 0 °C → 20 °C; 20 °C → 0 °C
1.2 24 h, 0 °C

参考文献：

Mesoscale Block Copolymers

Barber, Dylan M.; et al, Advanced Materials (Weinheim, 2018, 30(13),

合成路线：1 步

_96%

反应条件：

1.1 Reagents: Potassium tert-butoxide Solvents: Tetrahydrofuran
1.2 Solvents: Tetrahydrofuran

参考文献：

Synthesis of para-tert-butoxycarbonyloxystyrene

, European Patent Organization, , ,

合成路线：1 步

2628-17-3

_97%

反应条件：

1.1 Reagents: Potassium carbonate Solvents: Tetrahydrofuran ; 24 h, rt

参考文献：

Effect of glass transition temperature on heat-responsive gas bubbles formation from polymers containing tert-butoxycarbonyl moiety

Iseki, Masashi; et al, Journal of Applied Polymer Science, 2018, 135(19),

合成路线：1 步

2628-17-3

_94%

反应条件：

1.1 Reagents: Potassium carbonate Solvents: Tetrahydrofuran ; 24 h, rt

参考文献：

Thermal degradation behavior of polymers containing tert-butoxycarbonyl group in side chain and application to dismantlable adhesion materials

Suzuki, Fumiya; et al, Nippon Setchaku Gakkaishi, 2017, 53(1), 4-10

合成路线：1 步

87188-50-9

74-95-3

_87%

反应条件：

1.1 Reagents: Acetyl chloride , Zinc Solvents: Dimethylformamide

参考文献：

Method for producing hydroxystyrene derivatives from hydroxybenzaldehyde derivatives and dibromomethane

, Japan, , ,

合成路线：1 步

7400-08-0

_90%

反应条件：

1.1 Reagents: Hydroquinone , Potassium acetate Solvents: Dimethylformamide ; rt → 130 °C; 1.5 h, 130 °C; 130 °C → 50 °C
1.2 50 °C; 2 h, 50 °C
1.3 Reagents: Water ; cooled

参考文献：

Study on the synthetic process of monomers of p-hydroxystyrene and its derivatives for 248 nm photoresist

Song, Guoqiang; et al, Huagong Xinxing Cailiao, 2011, 39(7), 85-87

合成路线：1 步

74-83-9

87188-50-9

_70%

反应条件：

1.1 Reagents: Triphenylphosphine , Potassium tert-butoxide Solvents: Diethyl ether ; 10 min, rt; 10 min, rt
1.2 Solvents: Tetrahydrofuran ; rt; 1 h, rt

参考文献：

Synthetic improvement of [[(tert-butoxy)carbonyl]oxy]styrene intermediate of monomer of poly (p-hydroxystyrene)

Liu, Jian-Guo; et al, Yingyong Huaxue, 2007, 24(3), 361-364

合成路线：1 步

1133149-52-6

_60%

反应条件：

1.1 Catalysts: Potassium tert-butoxide Solvents: Tetrahydrofuran ; 1 h, rt → 40 °C
1.2 Reagents: Water ; cooled

参考文献：

A novel synthesis of p-tert-butoxycarbonyloxystyrene

Liu, Jian-Guo; et al, Yingyong Huaxue, 2008, 25(4), 424-428

合成路线：2 步

141-82-2

123-08-0

反应条件：

1.1 Catalysts: Piperidine Solvents: 4-Methylpyridine ; rt → 85 °C; 1.5 h, 85 °C; cooled
1.2 Reagents: Potassium carbonate Solvents: Water
1.3 Reagents: Hydrochloric acid Solvents: Water ; pH 2
2.1 Reagents: Hydroquinone , Potassium acetate Solvents: Dimethylformamide ; rt → 130 °C; 1.5 h, 130 °C; 130 °C → 50 °C
2.2 50 °C; 2 h, 50 °C
2.3 Reagents: Water ; cooled

参考文献：

Study on the synthetic process of monomers of p-hydroxystyrene and its derivatives for 248 nm photoresist

Song, Guoqiang; et al, Huagong Xinxing Cailiao, 2011, 39(7), 85-87

合成路线：2 步

224824-55-9

反应条件：

1.1 Reagents: N-Bromosuccinimide Catalysts: Benzoyl peroxide Solvents: Carbon tetrachloride ; rt → 90 °C; 90 °C; 90 °C → rt
2.1 Catalysts: Potassium tert-butoxide Solvents: Tetrahydrofuran ; 1 h, rt → 40 °C
2.2 Reagents: Water ; cooled

参考文献：

A novel synthesis of p-tert-butoxycarbonyloxystyrene

Liu, Jian-Guo; et al, Yingyong Huaxue, 2008, 25(4), 424-428

合成路线：2 步

58765-11-0

反应条件：

1.1 Solvents: Tetrahydrofuran ; 1 h, rt
1.2 Reagents: Water ; cooled
2.1 Reagents: Triphenylphosphine , Potassium tert-butoxide Solvents: Diethyl ether ; 10 min, rt; 10 min, rt
2.2 Solvents: Tetrahydrofuran ; rt; 1 h, rt

参考文献：

Synthetic improvement of [[(tert-butoxy)carbonyl]oxy]styrene intermediate of monomer of poly (p-hydroxystyrene)

Liu, Jian-Guo; et al, Yingyong Huaxue, 2007, 24(3), 361-364

合成路线：2 步

反应条件：

1.1 Reagents: Ammonium acetate Solvents: Methanol , Water ; 24 h, rt
2.1 Reagents: Potassium carbonate Solvents: Tetrahydrofuran ; 24 h, rt

参考文献：

Effect of glass transition temperature on heat-responsive gas bubbles formation from polymers containing tert-butoxycarbonyl moiety

Iseki, Masashi; et al, Journal of Applied Polymer Science, 2018, 135(19),

合成路线：2 步

反应条件：

1.1 Reagents: Ammonium hydroxide Solvents: Methanol ; 24 h, rt
2.1 Reagents: Potassium carbonate Solvents: Tetrahydrofuran ; 24 h, rt

参考文献：

Thermal degradation behavior of polymers containing tert-butoxycarbonyl group in side chain and application to dismantlable adhesion materials

Suzuki, Fumiya; et al, Nippon Setchaku Gakkaishi, 2017, 53(1), 4-10

合成路线：3 步

123-07-9