93-92-5 (乙酸苏合香酯,Styralyl Acetate)

_100%

反应条件：

1.1 Catalysts: 4-Pyridinamine, N-[(4-ethenylphenyl)methyl]-N-methyl-, polymer with 4-ethenyl-N,… Solvents: Toluene ; rt; 1 h, rt

参考文献：

Chromatography-free esterification reactions using a bifunctional polymer

Ma, Shuang; Toy, Patrick H., Synlett, 2016, 27(8), 1207-1210

合成路线：1 步

_100%

反应条件：

1.1 Catalysts: Silica ; 10 min, rt

参考文献：

Highly efficient solvent-free acetylation of alcohols with acetic anhydride catalyzed by recyclable sulfonic acid catalyst (SBA-15-Ph-Pr-SO3H) - An environmentally benign method

Zareyee, Daryoush; Ghadikolaee, Abdollah Razaghi; Khalilzadeh, Mohammad A., Canadian Journal of Chemistry, 2012, 90(5), 464-468

合成路线：1 步

2206-94-2

_100%

反应条件：

1.1 Catalysts: Diethylamine , (T-4)-[[(1R,4S)-4-[[(1,1-Dimethylethyl)diphenylsilyl]oxy]-2-(diphenylphosphino-κ… Solvents: Diethylamine ; 2 h, 40 °C
1.2 Catalysts: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium Solvents: Ethanol , Methanol ; 1 h, rt
1.3 Catalysts: Sodium tetrafluoroborate Solvents: Water ; rt; 1.5 h, rt
1.4 Reagents: Hydrogen Solvents: Methanol ; 10 h, 100 psi, 50 °C

参考文献：

Chemoenzymatic synthesis of a mixed phosphine-phosphine oxide catalyst and its application to asymmetric allylation of aldehydes and hydrogenation of alkenes

Boyd, Derek R.; Bell, Mark; Dunne, Katherine S.; Kelly, Brian; Stevenson, Paul J.; et al, Organic & Biomolecular Chemistry, 2012, 10(7), 1388-1395

合成路线：1 步

108-05-4

_100%

反应条件：

1.1 Solvents: Toluene ; 10 h, 40 °C

参考文献：

Dynamic kinetic resolution of secondary aromatic alcohols with new efficient acyl donors

Xu, Gang; Chen, Yong-Jun; Wu, Jian-Ping; Cheng, Yong-Mei; Yang, Li-Rong, Tetrahedron: Asymmetry, 2011, 22(13), 1373-1378

合成路线：1 步

2206-94-2

_100%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(1R,1′R)-1,1′-(1,2-ethanediyl)bis[… Solvents: Methanol ; 50 °C

参考文献：

Preparation of ethylene bridged Chiral bisphosphines as ligands

, World Intellectual Property Organization, , ,

合成路线：1 步

_100%

反应条件：

1.1 Catalysts: Dodecatangestocobaltate trihydrate (K5CoW12O40 3H2O) Solvents: Acetonitrile
1.2 Reagents: Sodium bicarbonate Solvents: Water
1.3 Solvents: Diethyl ether

参考文献：

Catalytic acetylation of alcohols and phenols with potassium dodecatungstocobaltate trihydrate

Habibi, Mohammad H.; Tangestaninejad, Shahram; Mirkhani, Valiollah; Yadollahi, Bahram, Monatshefte fuer Chemie, 2002, 133(3), 323-327

合成路线：1 步

22306-37-2

585-71-7

_100%

反应条件：

1.1 Solvents: Carbon tetrachloride

参考文献：

Bi(III) carboxylates as efficient reagents for preparation of esters under mild conditions. A new method for the protection of carboxylic acids

Keramane, E.-M.; Boyer, B.; Roque, J.-P., Tetrahedron Letters, 2001, 42(5), 855-857

合成路线：1 步

_100%

反应条件：

1.1 Catalysts: Iodine Solvents: Chloroform , Dichloromethane
1.2 Reagents: Water

参考文献：

Iodine as an acetyl transfer catalyst

Borah, Ruli; Deka, Nabajyot; Sarma, Jadab C., Journal of Chemical Research, 1997, (3), 110-111

合成路线：1 步

98-86-2

75-36-5

_100%

反应条件：

1.1 Solvents: Benzene

参考文献：

Reductive acylation of ketones. II

Kaplan, Leonard, Journal of the American Chemical Society, 1966, 88(21), 4970-1

合成路线：1 步

141-78-6

_99%

反应条件：

1.1 Reagents: Manganese Catalysts: Titanocene dichloride Solvents: Tetrahydrofuran ; 15 min, rt
1.2 Reagents: Diiodomethane Solvents: Tetrahydrofuran ; 2.5 h, rt
1.3 1.5 h, rt

参考文献：

Efficient O-Acylation of Alcohols and Phenol Using Cp2TiCl as a Reaction Promoter

Duran-Pena, Maria Jesus; Botubol-Ares, Jose Manuel; Hanson, James R. ; Hernandez-Galan, Rosario; Collado, Isidro G., European Journal of Organic Chemistry, 2016, 2016(21), 3584-3591

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Triethylamine Catalysts: 4-(Dimethylamino)pyridine Solvents: Diethyl ether ; rt

参考文献：

The effect of the migrating group structure on enantioselectivity in lipase-catalyzed kinetic resolution of 1-phenylethanol

Melais, Nedjma; Aribi-Zouioueche, Louisa; Riant, Olivier, Comptes Rendus Chimie, 2016, 19(8), 971-977

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: 1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, compd. with 4-(1-pyrrolidinyl)pyridin… ; 1 h, 22 °C

参考文献：

Pyridinium saccharinate salts as efficient recyclable acylation catalyst: a new bridge between heterogeneous and homogeneous catalysis

Lu, Norman; Chang, Wei-Hsuan; Wei, Rong-Jyun; Fang, Yung-Cheng; Han, Tu-Wen; et al, Tetrahedron, 2016, 72(24), 3468-3476

合成路线：1 步

108-22-5

_99%

反应条件：

1.1 Catalysts: Potassium tert-butoxide , (1-Butyl-3-cyclohexyl-1,3-dihydro-2H-imidazol-2-ylidene)dichloro[(1,2,3,4,5,6-η)… Solvents: Toluene ; 10 min, rt
1.2 Reagents: Sodium carbonate Solvents: Water ; 4 h, 25 °C

参考文献：

Selectivity Enhancement in Dynamic Kinetic Resolution of Secondary Alcohols through Adjusting the Micro-Environment of Metal Complex Confined in Nanochannels: A Promising Strategy for Tandem Reactions

Cao, Hui; Zhu, Xiao-Han; Wang, Dong; Sun, Zhenkun; Deng, Yonghui; et al, ACS Catalysis, 2015, 5(1), 27-33

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: 1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, compd. with N,N-dimethyl-4-pyridinami… ; 2 h, 25 °C

参考文献：

Recyclable catalysts for esterification or acylation of alcohols

, United States, , ,

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: 4-Pyridinamine, 3,5-dibromo-N,N-dimethyl-, polymer with 1,3,5-triethynylbenzene ; 10 h, rt

参考文献：

4-(N,N-Dimethylamino)pyridine-Embedded Nanoporous Conjugated Polymer as a Highly Active Heterogeneous Organocatalyst

Zhang, Yuan; Zhang, Yong; Sun, Ya Lei; Du, Xin; Shi, Jiao Yi; et al, Chemistry - A European Journal, 2012, 18(20), 6328-6334

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: Silver triflate ; 1 min, 60 °C

参考文献：

Silver triflate catalyzed acetylation of alcohols, thiols, phenols, and amines

Das, Rima; Chakraborty, Debashis, Synthesis, 2011, (10), 1621-1625

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: 1,2-Benzisothiazol-3(2H)-one, 1,1-dioxide, compd. with N,N-dimethyl-4-pyridinami… ; 2 h, 25 °C

参考文献：

A salt made of 4-N,N-dimethylaminopyridine (DMAP) and saccharin as an efficient recyclable acylation catalyst: a new bridge between heterogeneous and homogeneous catalysis

Lu, Norman; Chang, Wei-Hsuan; Tu, Wen-Han; Li, Chieh-Keng, Chemical Communications (Cambridge, 2011, 47(25), 7227-7229

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: Methylenediphosphonic acid ; 2 h, rt

参考文献：

Process for preparation of fatty alcohol esters by bisphosphonic acid-catalyzed esterification

, China, , ,

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: Thallium chloride (TlCl3) ; 6 min, rt

参考文献：

Thallium(III) chloride: a mild and efficient catalyst for acylation of alcohols, phenols and thiols, and for geminal diacylation of aldehydes under solvent-free conditions

Kadam, Santosh T.; Kim, Sung Soo, Synthesis, 2008, (20), 3307-3313

合成路线：1 步

_99%