94-46-2 (苯甲酸异戊酯,Isopentyl benzoate)

_99%

反应条件：

1.1 Catalysts: 1-Octanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, scand… Solvents: Isoamyl alcohol , Perfluorodecalin ; 6 h, 100 °C

参考文献：

Esterification of fluorous biphasic system catalyzed by rare earth(III) perfluorooctanesulfonates

Yi, Wen-Bin; Cai, Chun, Youji Huaxue, 2005, 25(11), 1434-1436

合成路线：1 步

58303-59-6

_99%

反应条件：

1.1 Catalysts: 2,4,6-Trimethylpyridine , 2,2-Bis(tert-butylperoxy)butane , tert-Dodecyl mercaptan Solvents: Octane

参考文献：

Radical-chain redox rearrangement of cyclic benzylidene acetals to benzoate esters in the presence of thiols

Roberts, B. P.; Smits, T. M., Tetrahedron Letters, 2001, 42(1), 137-140

合成路线：1 步

反应条件：

1.1 Reagents: Potassium bis(trimethylsilyl)amide Solvents: Tetrahydrofuran ; 2 min, cooled; 15 min, -78 °C
1.2 30 min, -78 °C; 4 h, -78 °C → 0 °C

参考文献：

Enolate-Based Regioselective Anti-Beckmann C-C Bond Cleavage of Ketones

Masek, Tomas; Jahn, Ullrich, Journal of Organic Chemistry, 2021, 86(17), 11608-11632

合成路线：1 步

5205-11-8

_98%

反应条件：

1.1 Reagents: Ethanol , Phenylsilane Catalysts: Thiophenol , Iron(III) acetylacetonate Solvents: 1-Propanol ; 46 h, 23 °C

参考文献：

Hydrogenation of Alkenes via Cooperative Hydrogen Atom Transfer

Kattamuri, Padmanabha V. ; West, Julian G., Journal of the American Chemical Society, 2020, 142(45), 19316-19326

合成路线：1 步

_98%

反应条件：

1.1 Reagents: 1H-Imidazolium, 3-[2-[(chloromethylene)methylammonio]ethyl]-1-methyl-, chloride,… Solvents: Dichloromethane ; 10 °C; 45 min, 10 °C
1.2 Solvents: Dichloromethane ; 25 °C; 15 min, 25 °C

参考文献：

Ionic liquid based Vilsmeier reagent as an efficient reagent for esterification of alcohols and carboxylic acids

Hullio, Ahmed Ali; Mastoi, G. M.; Imran, Hassan, International Journal of Organic Chemistry, 2018, 8(1), 125-134

合成路线：1 步

_98%

反应条件：

1.1 Catalysts: Pyridinium, 1-(phenylmethyl)-, phosphate (1:1) ; 15 min, 80 - 110 °C

参考文献：

Solvent-free synthesis of benzoic esters and benzyl esters in novel Bronsted acidic ionic liquids under microwave irradiation

Li, Xinzhong; Eli, Wumanjiang; Li, Gang, Catalysis Communications, 2008, 9(13), 2264-2268

合成路线：1 步

_98%

反应条件：

1.1 Catalysts: Titanium sulfate (Ti(SO4)2) ; 3 h, 132 °C

参考文献：

New green technology: synthesis of isoamyl benzoate catalyzed by titanium sulfate

Deng, Bin; Li, Qiangguo; Hu, Zhengshui, Baoji Wenli Xueyuan Xuebao, 2003, 23(1), 30-32

合成路线：1 步

_98%

参考文献：

Improved process for synthesizing isoamyl benzoate by direct esterification

Li, Xiuyu; Hua, Yuanyuan; Cao, Ming, Guangzhou Huagong, 2000, 28(4), 4-5

合成路线：1 步

98-88-4

_97%

反应条件：

1.1 Catalysts: Copper(4+), [1,8,15,22-tetramethyl-29H,31H-tetrapyrido[2,3-b:2′,3′-g:2′′,3′′-l:2… Solvents: Acetonitrile ; 23 h, reflux

参考文献：

Chemoselective protocol for O-acylation with a new catalyst

Akhlaghinia, Batool; Safaei, Elham; Larki, Paria, Trends in Organic Chemistry, 2010, 14, 93-106

合成路线：1 步

_97%

反应条件：

1.1 Catalysts: Silica , Titanium sulfate (Ti(SO4)2) ; 90 min, 140 °C

参考文献：

Synthesis of isoamyl benzoate catalyzed by Ti(SO4)2/SiO2

Zhang, Fu-juan; Zhang, Hong-yu; Sheng, Shu-ling; Zhang, Xiang-yu, Gongye Cuihua, 2004, 12(11), 24-26

合成路线：1 步

_96%

反应条件：

1.1 Catalysts: 1-Octanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, ytter… Solvents: Toluene , Perfluorodecalin ; 5 min, rt; 6 h, 100 °C; 100 °C → rt

参考文献：

Polymer-supported ytterbium perfluorooctanesulfonate [Yb(OPf)3]: A recyclable catalyst for organic reactions

Yi, Wen-Bin; Cai, Chun, Journal of Fluorine Chemistry, 2008, 129(6), 524-528

合成路线：1 步

_96%

反应条件：

1.1 Reagents: Sulfuric acid , Permanganic acid (HMnO4), potassium salt (1:1) Catalysts: Graphite ; 2 h, reflux

参考文献：

A novel method for the synthesis of carboxylic esters catalyzed by expandable graphite

Zhang, Ying Qun; Wang, Chun; Li, Gui Shen, Chinese Chemical Letters, 2003, 14(1), 17-19

合成路线：1 步

_96%

反应条件：

1.1 Reagents: Water Solvents: Toluene

参考文献：

Synthesis of isoamyl benzoate catalyzed by tungstosilicic acid

Liu, Xinhe; Wang, Xueqin, Huagong Shikan, 2000, 14(6), 30-32

合成路线：1 步

58303-59-6

_94%

反应条件：

1.1 Reagents: Dimethyl disulfide Solvents: Benzene ; 24 h, rt

参考文献：

Bis(pentafluorophenyl) disulfide as a hydrogen abstractor and an electron acceptor from the resulting radical intermediate

Tada, Masaru; Katayama, Emi; Sakurai, Naoto; Murofushi, Keita, Tetrahedron Letters, 2004, 45(1), 17-19

合成路线：1 步

_93%

反应条件：

1.1 Catalysts: Ammonium ferric sulfate dodecahydrate Solvents: Isoamyl alcohol ; 3 h, reflux

参考文献：

Preparation of isoamyl benzoate using ammonium ferric sulfate dodecahydrate as a catalyst

Yang, Xiaolin; Li, Yunshan, Huagong Shikan, 2006, 20(4), 40-41

合成路线：1 步

5205-04-9

_92%

反应条件：

1.1 Reagents: Phenylsilane , Triethylsilyl chloride , Zinc Catalysts: Cyclopentadienyltitanium trichloride Solvents: 1,4-Dioxane ; 6 h, 60 °C

参考文献：

Ti-Catalyzed Dehydroxylation of Tertiary Alcohols

Lin, Quan; Tong, Weiqi ; Shu, Xing-Zhong ; Chen, Yunrong, Organic Letters, 2022, 24(46), 8459-8464

合成路线：1 步

98-88-4

_92%

反应条件：

1.1 Reagents: Triethylamine Catalysts: 4-(Dimethylamino)pyridine Solvents: Dichloromethane ; 0 °C; overnight, rt
1.2 Reagents: Water

参考文献：

Benzoates as photosensitization catalysts and auxiliaries in efficient, practical, light-powered direct C(sp3)-H fluorinations

Yakubov, Shahboz; Stockerl, Willibald J.; Tian, Xianhai; Shahin, Ahmed; Mandigma, Mark John P.; et al, Chemical Science, 2022, 13(47), 14041-14051

合成路线：1 步

532-32-1

_92%

反应条件：

1.1 Reagents: 1H-Imidazolium, 3-[2-[(chloromethylene)methylammonio]ethyl]-1-methyl-, chloride,… Solvents: Dichloromethane ; 25 °C
1.2 1.2 h, 25 °C

参考文献：

Ionic Liquid Based Vilsmeier Reagent as a Substitute for Mitsunobu Reagent: Direct Conversion of Alcohols into Different Compounds under Ionic Liquid Conditions

Hullio, Ahmed Ali; Mastoi, G. M., International Journal of Chemistry (Toronto, 2013, 5(3), 57-69

合成路线：1 步

2268705-27-5

_91%

反应条件：

1.1 Reagents: Diphenylsilane , Magnesium chloride Catalysts: 2-(2′-Pyridyl)benzimidazole , Zinc , Nickel dichloride Solvents: Dimethylacetamide ; 8 h, 60 °C

参考文献：

Hydrogenation reduction method of tertiary alkyl alcohol in presence of zinc powder/magnesium chloride

, China, , ,

合成路线：1 步

64548-92-1

_90%