947150-46-1 (S-(11-Bromoundecyl) ethanethioate,S-(11-bromoundecyl) Ethanethioate)

_97%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Toluene ; 2 h, 90 °C

参考文献：

"Precipitation on Nanoparticles": Attractive Intermolecular Interactions Stabilize Specific Ligand Ratios on the Surfaces of Nanoparticles

Chu, Zonglin ; Han, Yanxiao ; Kral, Petr; Klajn, Rafal, Angewandte Chemie, 2018, 57(24), 7023-7027

合成路线：1 步

_96%

反应条件：

1.1 Solvents: Toluene ; rt → 55 °C
1.2 Catalysts: Azobisisobutyronitrile ; 4 h, 55 °C → 80 °C

参考文献：

Redox-active organic-inorganic hybrid polyoxometalate micelles

Kastner, Katharina; Kibler, Alexander J.; Karjalainen, Erno; Fernandes, Jesum A.; Sans, Victor; et al, Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2017, 5(23), 11577-11581

合成路线：1 步

_92%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Toluene ; 4 h, reflux

参考文献：

Click chemistry-assisted self-assembly of DNA aptamer on gold nanoparticles-modified screen-printed carbon electrodes for label-free electrochemical aptasensor

Xie, Danping; Li, Congcong; Li, Shangguan; Qi, Honglan; Xue, Dong; et al, Sensors and Actuators, 2014, 192, 558-564

合成路线：1 步

_92%

反应条件：

1.1 Reagents: Azobisisobutyronitrile Solvents: Toluene ; 4 h, reflux; cooled

参考文献：

Facile Functionalization of Gold Nanoparticles via Microwave-Assisted 1,3 Dipolar Cycloaddition

Sommer, William J.; Weck, Marcus, Langmuir, 2007, 23(24), 11991-11995

合成路线：1 步

_90%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Toluene ; 6 h, rt → reflux; reflux → rt
1.2 Solvents: Water ; rt

参考文献：

Calix[4]arene-Functionalised Silver Nanoparticles as Hosts for Pyridinium-Loaded Gold Nanoparticles as Guests

Vita, Francesco; Boccia, Alice; Marrani, Andrea G.; Zanoni, Robertino; Rossi, Francesca; et al, Chemistry - A European Journal, 2015, 21(43), 15428-15438

合成路线：1 步

_87%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Toluene ; 4 h, reflux

参考文献：

Click' Preparation of CuPt Nanorod-Anchored Graphene Oxide as a Catalyst in Water

Yang, Hyunseung; Kwon, Yongwoo; Kwon, Taegyun; Lee, Hyunjoo; Kim, Bumjoon J., Small, 2012, 8(20), 3161-3168

合成路线：1 步

_85%

反应条件：

1.1 Reagents: Azobisisobutyronitrile Solvents: Toluene ; 3 h, reflux

参考文献：

Tailoring the Properties of Surface-Immobilized Azobenzenes by Monolayer Dilution and Surface Curvature

Moldt, Thomas; Brete, Daniel; Przyrembel, Daniel; Das, Sanjib; Goldman, Joel R.; et al, Langmuir, 2015, 31(3), 1048-1057

合成路线：1 步

_83%

反应条件：

1.1 Reagents: Carbon tetrabromide , Triphenylphosphine Solvents: Dichloromethane ; 0 °C; 1 h, 25 °C
1.2 Reagents: Water ; 25 °C

参考文献：

AuBr3 mediated glycosidations: synthesis of tetrasaccharide motif of the Leishmania donovani lipophosphoglycan

Sureshkumar, Gopalsamy; Hotha, Srinivas, Glycoconjugate Journal, 2012, 29(4), 221-230

合成路线：1 步

_81%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Toluene ; 2 h, reflux

参考文献：

Microwave-Assisted Catalytic Acetylation of Alcohols by Gold-Nanoparticle-Supported Gadolinium Complex

Chang, Tsao-Ching; Yu, Shuchun Joyce, Synthetic Communications, 2015, 45(5), 651-662

合成路线：1 步

_72%

反应条件：

1.1 Reagents: Carbon tetrabromide , Triphenylphosphine , Phosphorus pentoxide Solvents: Dichloromethane ; 24 h, rt

参考文献：

Preparation of coumarin polymethyl methacrylate composite polymer and nano self-assembly application thereof

, China, , ,

合成路线：1 步

_72%

反应条件：

1.1 Reagents: Carbon tetrabromide , Triphenylphosphine Solvents: Dichloromethane ; 24 h, rt

参考文献：

Preparation method of thio-functionalized coumarin derivative used for preparation of coumarin functionalized gold nanoparticles

, China, , ,

合成路线：1 步

_72%

反应条件：

1.1 Reagents: Carbon tetrabromide , Triphenylphosphine Solvents: Dichloromethane ; 24 h, rt

参考文献：

Light-induced reversible self-assembly of gold nanoparticles surface-immobilized with coumarin ligands

He, Huibin; Feng, Miao ; Chen, Qidi; Zhang, Xinqi; Zhan, Hongbing, Angewandte Chemie, 2016, 55(3), 936-940

合成路线：1 步

_70%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Toluene ; 3 h, reflux

参考文献：

Effect of Chemical Binding of Doxorubicin Hydrochloride to Gold Nanoparticles, Versus Electrostatic Adsorption, on the In Vitro Drug Release and Cytotoxicity to Breast Cancer Cells

Zayed, Gamal M.; Kamal, Islam; Abdelhafez, Wael A.; Alsharif, Fahd M.; Amin, Mohamed A.; et al, Pharmaceutical Research, 2018, 35(6), 1-14

合成路线：1 步

_65%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Methanol , Toluene ; 8 h, reflux

参考文献：

Iron(II)-α-keto acid complexes of tridentate ligands on gold nanoparticles: the effect of ligand geometry and immobilization on their dioxygen-dependent reactivity

Bera, Abhijit; Sheet, Debobrata; Paine, Tapan Kanti, Dalton Transactions, 2023, 52(4), 1062-1073

合成路线：1 步

116129-34-1

_64%

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Toluene ; 1 h, 120 °C

参考文献：

Tuning the Tunneling Rate and Dielectric Response of SAM-Based Junctions via a Single Polarizable Atom

Wang, Dandan; Fracasso, Davide; Nurbawono, Argo; Annadata, Harshini V.; Sangeeth, C. S. Suchand; et al, Advanced Materials (Weinheim, 2015, 27(42), 6689-6695

合成路线：1 步

16696-65-4

10387-40-3

_63%

反应条件：

1.1 Solvents: Acetone ; 12 h, rt

参考文献：

High-Yield Excited Triplet States in Pentacene Self-Assembled Monolayers on Gold Nanoparticles through Singlet Exciton Fission

Kato, Daiki; Sakai, Hayato; Tkachenko, Nikolai V.; Hasobe, Taku, Angewandte Chemie, 2016, 55(17), 5230-5234

合成路线：1 步

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Methanol ; 15 h, 70 °C

参考文献：

Interfacial charge regulation of protein blocking layers in transistor biosensor for direct measurement in serum

Park, Sungwook; Kim, Minsoo; Kim, Dongkap; Kang, Seok Ho; Lee, Kwan Hyi; et al, Biosensors & Bioelectronics, 2020, 147,

合成路线：1 步

反应条件：

1.1 Catalysts: Azobisisobutyronitrile Solvents: Methanol ; 12 h, rt

参考文献：

Immobilized aza-bis(oxazoline) copper catalysts on alkanethiol self-assembled monolayers on gold: Selectivity dependence on surface electronic environments

Paluti, Christy C.; Gawalt, Ellen S., Journal of Catalysis, 2010, 275(1), 149-157

合成路线：1 步