984-43-0 ([2-(二苯基膦)乙基]二苯基氧化膦,Phosphine oxide,[2-(diphenylphosphino)ethyl]diphenyl-)

CAS号:
984-43-0
中文名称:
[2-(二苯基膦)乙基]二苯基氧化膦
英文名称:
Phosphine oxide,[2-(diphenylphosphino)ethyl]diphenyl-
分子式:
C26H24OP2
分子量:
414.415688514709

[2-(二苯基膦)乙基]二苯基氧化膦(984-43-0)名称与标识符

名称

中文别名:
1,2-二(二苯基膦基)乙烷单氧化物;1,2-双(二苯基磷酰)乙烷氧化物;1,2-双(二苯基膦)乙烷一氧化物;1,2-双(二苯基膦基)乙烷;1,2-双(二苯基膦基)乙烷一氧化物;NG-羟基-L-精氨酸合乙酸;[2-(二苯基膦)乙基]二苯基氧化膦;
英文别名:
Phosphine oxide,[2-(diphenylphosphino)ethyl]diphenyl-;1,2-BIS(DIPHENYLPHOSPHINO)ETHANE MONOOXIDE;AURORA KA-1612;Tetraphenylethylenediphosphine monooxide;tetraphenylethylenediphosphine monoxide;[2-(diphenylphosphanyl)ethyl](diphenyl)phosphane oxide;ADS-J16;CS-0086082;(2-(Diphenylphosphino)ethyl)diphenylphosphine oxide;[2-(Diphenylphosphinoyl)ethyl]diphenylphosphane;1-(Diphenylphosphinoyl)-2-(diphenylphosphino)ethane;2-diphenylphosphorylethyl(diphenyl)phosphane;(2-(Diphenylphosphino)ethyl)diphenylphosphineoxide;1,2-Bis(diphenylphosphino)ethane monooxide, 97%;AKOS015913131;[2-(Diphenylphosphino)ethyl]diphenylphosphine oxide;984-43-0;CHEMBL107880;SCHEMBL3264810;MFCD00345406;JCAUAUKUBUBNSB-UHFFFAOYSA-N;[2-(diphenylphosphoroso)ethyl]diphenylphosphane;G75965;

标识符

MDL:
MFCD00345406
InChIKey:
JCAUAUKUBUBNSB-UHFFFAOYSA-N
Inchi:
1S/C26H24OP2/c27-29(25-17-9-3-10-18-25,26-19-11-4-12-20-26)22-21-28(23-13-5-1-6-14-23)24-15-7-2-8-16-24/h1-20H,21-22H2
SMILES:
P(C1C=CC=CC=1)(C1C=CC=CC=1)(CCP(C1C=CC=CC=1)C1C=CC=CC=1)=O

[2-(二苯基膦)乙基]二苯基氧化膦(984-43-0)物化性质

实验特性

  • LogP : 5.13340
  • PSA : 40.47000
  • 熔点 : 195-199 °C (lit.)

计算特性

  • 精确分子量 : 414.13000
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 7
  • 同位素质量 : 414.13023938g/mol
  • 重原子数量 : 29
  • 复杂度 : 469
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 5.3
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 17.1Ų

[2-(二苯基膦)乙基]二苯基氧化膦(984-43-0)安全信息

[2-(二苯基膦)乙基]二苯基氧化膦(984-43-0)海关数据

海关编码:
2902909090
海关数据:

中国海关编码:

2902909090

概述:

2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%

申报要素:

品名, 成分含量

Summary:

2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

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[2-(二苯基膦)乙基]二苯基氧化膦(984-43-0) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       1,2-Bis(diphenylphosphino)ethane monooxide, min. 97%    
   CAS Registry Number:       984-43-0    
   Formula:       (C6H5)2PCH2CH2P(O)(C6H5)2    
   EINECS Number:       none    
   Chemical Family:       organophosphine ligand    
   Synonym:       [2-(Diphenylphosphino)ethyl]diphenylphosphine oxide; [2-(Diphenyl-phosphinoyl)-ethyl]-diphenyl-phosphane    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       984-43-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Inhalation, skin, eyes.    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes irritation of the skin. May cause redness, itching and pain.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white powder    
   Molecular Weight:       414.42    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       no data    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, phosphorous pentoxide, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A