1445085-55-1
XPhos PdG3
Synonym: (2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, 
XPhos-G3-Palladacycle, 
XPhos-Pd-G3

CAS Number: 1445085-55-1
Formula: C46H62NO3PPdS
Formula Weight: 846.45 g/mol
Appearance (Color) White to Grey and Faint Beige to Beige powder
Caution : air sensitive 
shelf life :12 month 
Supplier: LPBchem-Benjamin
assay 95%
mp 146-151 °C (decomposition)
ISO9001 Manufacturer 
Standard laboratory 
ligands catalysts synthesis compounds

Related Categories
Buchwald 3rd Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
Homogeneous Pd Catalysts, Palladium Catalysts

General description
XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Application
XPhos Pd G3 may be used in the following reactions: 
1.Cyanation reaction of heterocyclic halides.
2 Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
3 Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.