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A decacobalt(ii) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(ii/iii) Weakley-type polyoxometalate†
Yan Duan,Juan M. Clemente-Juan,José L. G. Fierro,Carlos Giménez-Saiz,Eugenio Coronado
Chemical Communications Pub Date : 10/14/2016 00:00:00 , DOI:10.1039/C6CC05485D
Abstract

Partial reductive hydrolysis of a penta-CoII/III cluster [CoII4(H2O)2(CoIIIW9O34)(PW9O34)]12− (1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22− (2). This polyoxometalate is made up of two capping [PW9O34]9− units and two bridging [W7O26]10− units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.

Graphical abstract: A decacobalt(ii) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(ii/iii) Weakley-type polyoxometalate
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