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Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines†
Linfeng Cui,Yang'en You,Xueling Mi,Sanzhong Luo
Organic Chemistry Frontiers Pub Date : 06/15/2018 00:00:00 , DOI:10.1039/C8QO00496J
Abstract

A simple chiral primary amine catalyst was identified to enable effective catalysis in direct α-sulfenylation of acyclic and cyclic β-ketocarbonyls with good yields and excellent enantioselectivities.

Graphical abstract: Catalytic enantioselective α-sulfenylation of β-ketocarbonyls by chiral primary amines
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