“Inosaminoacids”: novel inositol–amino acid hybrid structures accessed by microbial areneoxidation†
Sarah Pilgrim,Gabriele Kociok-Köhn,Matthew D. Lloyd,Simon E. Lewis
Chemical Communications Pub Date : 03/15/2011 00:00:00 , DOI:10.1039/C1CC10643K
Abstract
Microbial 1,2-dihydroxylation of sodium benzoate permits the rapid construction of novel inositol–amino acid hybrid structures. Both β- and γ-amino acids are accessible by means of an acylnitroso Diels–Alder cycloaddition.