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Cooperative catalysis for the direct hydrodeoxygenation of vegetable oils into diesel-range alkanes over Pd/NbOPO4†
Xiaojing Zhuang,Molly Meng-Jung Li,Yung-Kang Peng,Guoliang Liu,Tai-Sing Wu,Yun-Liang Soo,Xue-Qing Gong,Yanqin Wang,Shik Chi Edman Tsang
Chemical Communications Pub Date : 03/08/2016 00:00:00 , DOI:10.1039/C5CC10419J
Abstract

Near quantitative carbon yields of diesel-range alkanes were achieved from the hydrodeoxygenation of triglycerides over Pd/NbOPO4 under mild conditions with no catalyst deactivation: catalyst characterization and theoretical calculations suggest that the high hydrodeoxygenation activity originated from the synergistic effect of Pd and strong Lewis acidity on the unique structure of NbOPO4.

Graphical abstract: Cooperative catalysis for the direct hydrodeoxygenation of vegetable oils into diesel-range alkanes over Pd/NbOPO4
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