A dual approach to tuning the porosity of porous organic polymers: controlling the porogen size and supercritical CO2 processing†,10.1039/C3SC52010B

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

A dual approach to tuning the porosity of porous organic polymers: controlling the porogen size and supercritical CO2 processing†

Ryan K. Totten,Laura L. Olenick,Ye-Seong Kim,Sanjiban Chakraborty,Mitchell H. Weston,Omar K. Farha,Joseph T. Hupp,SonBinh T. Nguyen

Chemical Science Pub Date : 10/09/2013 00:00:00 , DOI:10.1039/C3SC52010B

Abstract

Porous organic polymers (POPs) with tunable pore volumes and surface areas can be made from a series of Sn^IV(porphyrins) functionalized with labile, bulky trans-diaxial ligands. Varying the ligand size allows for the tuning of the micropore volume while supercritical CO₂ processing resulted in excellent enhancements of the total pore volumes.