Covalent surface modification of a metal–organic framework: selective surface engineering viaCuI-catalyzed Huisgen cycloaddition†
Tendai Gadzikwa,Guang Lu,Charlotte L. Stern,Scott R. Wilson,Joseph T. Hupp,SonBinh T. Nguyen
Chemical Communications Pub Date : 10/08/2008 00:00:00 , DOI:10.1039/B805101A
Abstract
A Zn-cornered, mixed-ligand, metal–organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via‘click chemistry’, in a demonstration of selective post-synthesis functionalization.
