960化工网
Continuous flow aerobic alcohol oxidation using a heterogeneous Ru0 catalyst†
Julien Sofack Kreutzer,Laurent Vanoye,Régis Philippe,Estelle Metay,Marie-Christine Duclos,Marc Lemaire,Claude De Bellefon,Pascal Fongarland
Reaction Chemistry & Engineering Pub Date : 11/30/2018 00:00:00 , DOI:10.1039/C8RE00212F
Abstract

The continuous selective aerobic oxidation of benzyl alcohol in flow was developed using an immobilized Ru0 catalyst. After optimization of the reaction conditions, the stability and productivity of the equipment were examined over time using tert-amyl alcohol as solvent, and no deactivation occurred. A cumulative TON close to 15 000 was obtained with a constant activity (TOF = 4 min−1). A semi-empirical kinetic rate expression was proposed.

Graphical abstract: Continuous flow aerobic alcohol oxidation using a heterogeneous Ru0 catalyst
平台客服
平台客服
平台在线客服