Conversion of methacrylate into 2-hydroxy-2-methylpropionate ligands in the coordination sphere of a Ag–Zr oxo cluster†
Christine Artner,Ayse Koyun,Ulrich Schubert
Dalton Transactions Pub Date : 03/28/2013 00:00:00 , DOI:10.1039/C3DT50554E
Abstract

Reaction of Zr(OnBu)4 and silver acetate with methacrylic acid afforded a mixed-metal cluster with a Ag2Zr8O6 core and both methacrylate and 2-hydroxy-2-methylpropionate ligands.

Graphical abstract: Conversion of methacrylate into 2-hydroxy-2-methylpropionate ligands in the coordination sphere of a Ag–Zr oxo cluster