1,2,3-Triphosphole derivatives as reactive intermediates†‡,10.1039/B822732B

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1,2,3-Triphosphole derivatives as reactive intermediates†‡

Markus Stubenhofer,Christian Kuntz,Gábor Balázs,Manfred Zabel,Manfred Scheer

Chemical Communications Pub Date : 02/05/2009 00:00:00 , DOI:10.1039/B822732B

Abstract

The complexes [Cp*E{W(CO)₅}₂] (E = P, As; Cp* = C₅Me₅) react with 1,2-diphosphinobenzene to give 1,2,3-triphosphole and 2-arsa-1,3-diphosphole derivatives as reactive intermediates that dimerise to polycyclic phosphorous and arsenic containing cage compounds.