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Copper(ii)-mediated chiral helicity amplification and inversion of meta-ethynylpyridinepolymers with metal coordination sites†
Shunsuke Takashima,Hajime Abe,Masahiko Inouye
Chemical Communications Pub Date : 05/31/2011 00:00:00 , DOI:10.1039/C1CC12358K
Abstract

meta-Ethynylpyridine polymers bearing metal coordination sites associate with alkyl glycoside guests to show induced circular dichroism (ICD) bands. The addition of a Cu(II) ion changed the intensity or the sign of these ICD bands. The changes suggested chiral helicity amplification or inversion of the polymers by Cu(II)-mediated cross-linking at the coordinating side chains.

Graphical abstract: Copper(ii)-mediated chiral helicity amplification and inversion of meta-ethynylpyridine polymers with metal coordination sites
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