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Cis double allylation of cyclopropenes using cyclopropylindium reagents
Tsunehisa Hirashita,Fumio Shiraki,Kenji Onishi,Mamiko Ogura,Shuki Araki
Organic & Biomolecular Chemistry Pub Date : 06/05/2007 00:00:00 , DOI:10.1039/B706539F
Abstract

The successive double allylation of cyclopropenes with allylindium sesquiiodide and allyl iodide proceeded with a cis-addition mode in the presence of other organometallics (e.g. Grignard reagent, cuprate, Et2Zn and Et3Al), giving the corresponding cis-diallylcyclopropanes in high yields.

Graphical abstract: Cis double allylation of cyclopropenes using cyclopropylindium reagents
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