Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors†,10.1039/C2CC34748B

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Cooperativity of H-bonding and anion–π interaction in the binding of anions with neutral π-acceptors†

Michael Giese,Markus Albrecht,Tim Krappitz,Marius Peters,Verena Gossen,Gerhard Raabe,Arto Valkonen,Kari Rissanen

Chemical Communications Pub Date : 09/04/2012 00:00:00 , DOI:10.1039/C2CC34748B

Abstract

A rare anion–π complex between bromide and a neutral receptor is reported and related receptor systems are studied with a series of anions. The interaction is observed in the solid state and in solution, and further evidence for it is obtained by a computational study.