Design, synthesis and structural investigation of a 2-D
coordination network based on the self-assembly of the tetracarboxylate
derivative of tetrathiacalix[4]arene and
Huriye Akdas,Ernest Graf,Mir Wais Hosseini,André De Cian,Jack McB. Harrowfield
Chemical Communications Pub Date : 11/01/2000 00:00:00 , DOI:10.1039/B007761P
Abstract
The fully deprotonated tetrathiacalix[4]arene 14− in 1,3-alternate conformation and bearing four carboxylate units was shown to act as a tecton leading, in the presence of Ag+cation, to a 2-D coordination network in the crystalline phase which can be described as discrete binuclear [14−, (Ag+)2]2− complexes interconnected by Ag+cations.
