Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand†,10.1039/C5CP01501D

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand†

Madanakrishna Katari,Eleonore Payen de la Garanderie,Edith Nicol,Vincent Steinmetz,Guillaume van der Rest,Duncan Carmichael,Gilles Frison

Physical Chemistry Chemical Physics Pub Date : 05/29/2015 00:00:00 , DOI:10.1039/C5CP01501D

Abstract

Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono–ligated complex has been demonstrated.