Counter-cation modulation of hydrogen and methane storage in a sodalite-type porous metal–organic framework†
Yun-Nan Gong,Miao Meng,Di-Chang Zhong,Yong-Liang Huang,Long Jiang,Tong-Bu Lu
Chemical Communications Pub Date : 11/05/2012 00:00:00 , DOI:10.1039/C2CC35461F
Abstract
A μ4-Cl bridged anionic sodalite-type porous metal–organic framework (Et2NH2)3[(Cu4Cl)3(TTCA)8]·26DEF was synthesized, in which Et2NH2+ can be exchanged by Li+cations. The results of gas measurements indicate that Et2NH2+ and Li+ are beneficial for methane and hydrogen storage, respectively.
