Cu2(BDC)2(BPY)–MOF: an efficient and reusable heterogeneous catalyst for the aerobic Chan–Lam coupling prepared via ball-milling strategy†,10.1039/C7RA09772G

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Cu2(BDC)2(BPY)–MOF: an efficient and reusable heterogeneous catalyst for the aerobic Chan–Lam coupling prepared via ball-milling strategy†

Armaqan Khosravi,Javad Mokhtari,Mohammad Reza Naimi-Jamal,Sharareh Tahmasebi,Leila Panahi

RSC Advances Pub Date : 09/28/2017 00:00:00 , DOI:10.1039/C7RA09772G

Abstract

Nanoporous Cu₂(BDC)₂(BPY)–MOF was used as efficient and reusable heterogeneous catalyst to effect the aerobic cross-coupling of aromatic amines and phenyl boronic acid (Chan–Lam coupling). Ball-milling strategy was utilized for the first as a powerful green and energy-efficient method for the synthesis of this nanoporous metal–organic framework. Certain ratio of metal ion and organic linkers were held to improve the quality of nanostructures. Cu₂(BDC)₂(BPY) were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET) surface area analysis.