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Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates†
Yan-Yan Sun,Jun Yi,Xi Lu,Zhen-Qi Zhang,Bin Xiao,Yao Fu
Chemical Communications Pub Date : 07/31/2014 00:00:00 , DOI:10.1039/C4CC05376A
Abstract

A copper-catalyzed Suzuki–Miyaura coupling of benzyl halides with arylboronates is described. Varieties of primary benzyl halides as well as more challenging secondary benzyl halides with β hydrogens or steric hindrance could be successfully converted into the corresponding products. Thus it provides access to diarylmethanes, diarylethanes and triarylmethanes.

Graphical abstract: Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates
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