A formal synthesis of (+)-pyripyropene A using a biomimetic epoxy-olefin cyclisation
Chemical Communications Pub Date : 01/01/1900 00:00:00 , DOI:10.1039/A808644C
Abstract
Bicyclic ester 2, a key intermediate in the first total synthesis of (+)-pyripyropene A 1, was synthesised from geraniol in 11 steps, utilising an epoxy-olefin biomimetic cyclisation as the key step.
