960化工网
Design and synthesis of graphene/SnO2/polyacrylamide nanocomposites as anode material for lithium-ion batteries
Yuanxin Wan,Tianyi Wang,Hongyan Lu,Xiaoqian Xu,Chen Zuo,Chao Teng
RSC Advances Pub Date : 03/27/2018 00:00:00 , DOI:10.1039/C8RA00958A
Abstract

Tin dioxide (SnO2) is a promising anode material for lithium-ion batteries owing to its large theoretical capacity (1494 mA h g−1). However, its practical application is hindered by these problems: the low conductivity, which restricts rate performance of the electrode, and the drastic volume change (400%). In this study, we designed a novel polyacrylamide/SnO2 nanocrystals/graphene gel (PAAm@SnO2NC@GG) structure, in which SnO2 nanocrystals anchored in three-dimensional graphene gel network and the polyacrylamide layers could effectively prevent the agglomeration of SnO2 nanocrystals, presenting excellent cyclability and rate performance. A capacity retention of over 90% after 300 cycles of 376 mA h g−1 was achieved at a current density of 5 A g−1. In addition, a stable capacity of about 989 mA h g−1 at lower current density of 0.2 A g−1 was achieved.

Graphical abstract: Design and synthesis of graphene/SnO2/polyacrylamide nanocomposites as anode material for lithium-ion batteries
平台客服
平台客服
平台在线客服