Diastereoselective solid-state crossed photocycloaddition of olefins in a 3D Zn(ii) coordination polymer†
Alexander D. Volodin,Ekaterina N. Zorina-Tikhonova,Aleksandr S. Chistyakov,Aleksei A. Sidorov,Anna V. Vologzhanina
Chemical Communications Pub Date : 11/19/2018 00:00:00 , DOI:10.1039/C8CC07734G
Abstract
1,2-Bis(4-pyridyl)ethylene undergoes a photoinitiated [2+2] cross-cycloaddition reaction with allyl groups of allylmalonate in pores of a 3D metal–organic framework (MOF) [Zn2(H2O)2(Amal)2(bpe)] to produce a 3D MOF with a new topology.
