Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]†,10.1039/C4CP03758H

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]†

Suzanne McMahon,Jonathan Rochford,Yvonne Halpin,Jennifer C. Manton,Emma C. Harvey,Gregory M. Greetham,Ian P. Clark,A. Denise Rooney,Conor Long,Mary T. Pryce

Physical Chemistry Chemical Physics Pub Date : 08/29/2014 00:00:00 , DOI:10.1039/C4CP03758H

Abstract

Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.