Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis†,10.1039/C5CC07767B

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis†

Neeraj Kumar Mishra,Miji Choi,Hyeim Jo,Yongguk Oh,Satyasheel Sharma,Sang Hoon Han,Taejoo Jeong,Sangil Han,Seok-Yong Lee,In Su Kim

Chemical Communications Pub Date : 10/08/2015 00:00:00 , DOI:10.1039/C5CC07767B

Abstract

The rhodium(III)-catalyzed direct functionalization of aniline C–H bonds with α-diazo compounds is described. These transformations provide a facile construction of ortho-alkylated anilines with diazo malonates or highly substituted indoles with diazo acetoacetates.